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https://www.selleckchem.com/products/phenol-red-sodium-salt.html The present approach can be applied to other water clusters and also to the low-lying vibrationally excited states and should help in the interpretation and assignment of experimental spectra in the future.2-Chloroethyl ethyl sulfide (CEES) is a simulant for the chemical warfare agent, bis(2-chloroethyl) sulfide, also known as mustard gas. Here, we demonstrate a facile and rapid method to synthesize a functionalized metal-organic framework (MOF) material for the detection of CEES at trace level. During the synthesis of Zr-BTC, the in situ encapsulation of a fluorescent material (fluorescein) into Zr-BTC voids is performed by a simple solvothermal reaction. The produced F@Zr-BTC is used as a fluorescent probe for CEES detection. The synthesized material shows fluorescence quenching under illumination at an excitation wavelength of 470 nm when F@Zr-BTC is exposed to CEES. This sensing material shows the highest fluorescence quenching at an emission wavelength of 534 nm with a CEES concentration as low as 50 ppb. Therefore, the demonstrated sensing method with F@Zr-BTC is a fast and convenient protocol for the selective and sensitive detection of CEES in practical applications.Intercalation-deintercalation of water-in-salt (WIS) electrolytes in nanoscale confinement is an important phenomenon relevant to energy storage and self-assembly applications. In this article, we use molecular simulations to investigate the effects of intersurface separation on the structure and free energy underlying the intercalation-deintercalation of the Li bis(trifluoromethane)sulfonimide ([Li][TFSI]) water-in-salt (WIS) electrolyte confined between nanoscale hydrophobic surfaces. We employ enhanced sampling to estimate the free energy profiles for the intercalation behaviour of WIS in confining sheets at several intersurface separations. We observe that the relative stability of the condensed and vapour phases of WIS in the c
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