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https://www.selleckchem.com/peptide/bulevirtide-myrcludex-b.html Strong metal-support interactions (SMSI) is an important concept in heterogeneous catalysis. Herein, we demonstrate that the Au-TiO2 SMSI of Au/TiO2 catalysts sensitively depends on both Au nanoparticle (NP) sizes and TiO2 facets. Au NPs of ca. 5 nm are more facile undergo Au-TiO2 SMSI than those of ca. 2 nm, while TiO2 001 and 100 facets are more facile than TiO2 101 facets. The resulting capsulating TiO2-x overlayers on Au NPs exhibit an average oxidation state between +3 and +4 and a Au-to-TiO2-x charge transfer, which, combined with calculations, determines the TiO ratio as ca. 611. Both TiO2-x overlayers and TiO2-x -Au interface exhibit easier lattice oxygen activation and higher intrinsic activity in catalyzing low-temperature CO oxidation than the starting Au-TiO2 interface. These results advance fundamental understanding of SMSI and demonstrate engineering of metal NP size and oxide facet as an effective strategy to tune the SMSI for efficient catalysis.Engineered probiotics have the potential to diagnose and treat a variety of gastrointestinal (GI) diseases. However, these exogenous bacterial agents have limited ability to effectively colonize specific regions of the GI tract due to a lack of external control over their localization and persistence. Magnetic fields are well suited to providing such control, since they freely penetrate biological tissues. However, they are difficult to apply with sufficient strength to directly manipulate magnetically labeled cells in deep tissue such as the GI tract. Here, it is demonstrated that a composite biomagnetic material consisting of microscale magnetic particles and probiotic bacteria, when orally administered and combined with an externally applied magnetic field, enables the trapping and retention of probiotic bacteria within the GI tract of mice. This technology improves the ability of these probiotic agents to accumulate at specific locations and

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