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https://www.selleckchem.com/products/Pyroxamide(NSC-696085).html 6 μs, and τ(III) = 3.6 μs. These data indicate that the spin-orbit coupling of state T1 with the singlet states is much stronger in the case of complex 5, which results in a much higher T1 → S0 emission rate. Indeed, a computational analysis suggests that in the dinuclear complex 5 the T1 state is spin-orbit coupled with twice the number of singlet states compared to that of mononuclear 3, which is a result of the electronic coupling of two coordination sites. The investigation of the temperature dependence of the emission rates of 3 and 5 shows that the room-temperature emission of both complexes is mainly contributed by a thermally populated excited state lying above the T1 state. To the best of our knowledge, complexes 3 and 5 are the first examples of Ir(III) complexes that show photophysical behavior reminiscent of thermally activated delayed fluorescence (TADF).C3-selective C-C bond formation on benzothiophenes is challenging, and few direct functionalization methods are available. A gold-catalyzed reaction of alkynes with benzothiophene S-oxides provides regioselective entry into C3-alkylated benzothiophenes with the C7-alkylated isomer as the minor product. This oxyarylation reaction works with alkyl and aryl alkynes and substituted and unsubstituted benzothiophenes. Mechanistic studies identify that sulfoxide inhibits the catalyst [DTBPAu(PhCN)]SbF6, which also degrades and forms the unreactive complex [(DTBP)2Au]SbF6.In the context of bacterial infections, it is imperative that physiological responses can be studied in an integrated manner, meaning a simultaneous analysis of both the host and the pathogen responses. To improve the sensitivity of detection, data-independent acquisition (DIA)-based proteomics was found to outperform data-dependent acquisition (DDA) workflows in identifying and quantifying low-abundant proteins. Here, by making use of representative bacterial pathogen/host prote

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