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https://www.selleckchem.com/products/pf-04620110.html This work provides a theoretical basis for designing sodium ion storage with a graphite layered structure and unveiling the prospects of MC-GIC materials as high-performance anodes.Fluorescent thermometers based on organic dyes play an important role in the visualization of dynamic temperature topography with high resolution. Many molecular thermometers contain two fluorophores with different temperature responses to achieve ratiometric temperature detection. However, the stability and reliability of such ratiometric thermometers are highly dependent on the susceptibility of the fluorophores towards photobleaching. Despite the use of single-fluorophore ratiometric thermometers in previous reports, the difficulty and complexity in their molecular design and synthesis severely hinder their widespread applicability. In this work, we have investigated the use of commercially available dyes (i.e., BD140 and LD688) with conformational isomers as ratiometric thermometers. Each of these dyes consists of a mixture of conformers with distinct UV-vis absorption and emission spectra. The thermal equilibrium of these conformers successfully enabled the development of ratiometric thermometers with good stability and reliability.Layered structures of flexible mixed-linker metal-organic frameworks termed IRHs-(4 and 5) (IRH = Institut de Recherche sur l'Hydrogène) were synthesized by mixing cyclam, tetrakis(4-carboxyphenyl)benzene (TCPB), and copper and zinc metal salts respectively. The new materials characterized by single-crystal X-ray diffraction exhibited the features of HOFs and MOFs. Their structures are formed by coordination and hydrogen bonds that link metallocyclam (with Cu or Zn) and TCPB to a 2D sheet which is further packed to form a 3D structure with 1D microchannels. Remarkably, the as-synthesized IRHs-(4 and 5) contain DMF in the channels that can be exchanged with DCM and afterward removed from the framework by
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