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https://www.selleckchem.com/products/pfk15.html Solid-state lithium (Li) batteries using spinel-oxide electrode materials such as LiNi0.5Mn1.5O4 are promising power supplies for mobile devices and electric vehicles. Here, we demonstrate stable battery cycling between the Li0Ni0.5Mn1.5O4 and Li2Ni0.5Mn1.5O4 phases with working voltages of approximately 2.9 and 4.7 V versus Li/Li+ in solid-state Li batteries with contamination-free clean Li3PO4/LiNi0.5Mn1.5O4 interfaces. This clean interface has the effect of doubling the capacity of conventional battery cycling between the Li0Ni0.5Mn1.5O4 and Li1Ni0.5Mn1.5O4 phases. We also investigated the structural changes between the Li0Ni0.5Mn1.5O4 and Li2Ni0.5Mn1.5O4 phases during battery cycling. Furthermore, we found an inhomogeneous distribution of the Li2Ni0.5Mn1.5O4 phase in the LiNi0.5Mn1.5O4 electrode, induced by spontaneous Li migration after the formation of the Li3PO4/LiNi0.5Mn1.5O4 interface. These results indicate that the formation of a contamination-free clean Li3PO4/LiNi0.5Mn1.5O4 interface is key to increase the battery capacity.Inflammation is an important protection reaction in living organisms associated with many diseases. Since peroxynitrite (ONOO-) is engaged in the inflammatory processes, illustrating the key nexus between ONOO- and inflammation is significant. Due to the lack of sensitive ONOO-in vivo detection methods, the research still remains at its infancy. Herein, a highly sensitive NIR fluorescence probe DDAO-PN for in vivo detection of ONOO- in inflammation progress was reported. The probe responded to ONOO- with significant NIR fluorescence enhancement at 657 nm (84-fold) within 30 s in solution. Intracellular imaging of exogenous ONOO- with the probe demonstrated a 68-fold fluorescence increase (F/F0). Impressively, the probe can in vivo detect ONOO- fluxes in LPS-induced rear leg inflammation with a 4.0-fold fluorescence increase and LPS-induced peritonitis with an 8.0-fold fluorescence increa
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