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https://www.selleckchem.com/products/AZD0530.html Furthermore, the PtSnBi nanoalloys with highlighted anti-CO poisoning capacity also improve the electrocatalytic performance toward EOR, indicating their great promise as broad energy electrocatalysts.Catalytic hydrogenation of sulfur-containing substrates is an important and challenging reaction in the chemical industry. In this work, active carbon supported PdZn alloy catalyst was prepared by self-reduction method using zinc acetate as precursor without H2 atmosphere. During the process of self-reduction, Zn2+ was firstly reduced to Zn0 at 300 °C by active carbon and reducing gas from the decompose of acetate under the promotion of metal Pd, and Zn0 further reacted with metal Pd to form PdZn alloy phase at 500 °C. These PdZn/AC-X catalysts showed the higher conversion and stability for the hydrogenation of 4-nitrothioanisole than the Pd/AC-600 catalyst. The excellent catalytic performance of PdZn/AC-600 catalyst can be attributed to formation of PdZn alloy, in which electron-rich Pd atoms weaken the binding ability between Pd and S and enhance the sulfur-resistance of catalyst. On the other hand, H2-TPR and DFT theory calculation further indicated that the PdZn alloy phase weakens the adsorption capacity of S. Compared with the Pd/AC-600 catalyst, the PdZn alloy phase in PdZn/AC-600 catalyst has not changed and only a small amount of sulfur-containing substrates deposited on the catalyst surface after three cycles. PdZn/AC-600 catalyst exhibited improved stability in the hydrogenation of 4-nitrothioanisole and can be used three cycles with little decrease in activity.The bionic application of electronic skin (e-skin) requires a high resolution close to that of human skin, while its long-term attachment to human body or robotic skin requires a porous structure that is air permeable and enables hair growth. To simultaneously meet the requirements of high resolution and porous structure, as well as improve the sensing
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