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Three-dimensional hierarchical porous carbon is prepared by utilizing enzymatic hydrolysis lignin as a carbon source via hydrothermal carbonization and activation. The complicated operational parameters including temperature, time, concentration and pH in the hydrothermal carbonization are systemically investigated. We employed the hydrochar as electrode for supercapacitors. Accordingly, we not only achieve a high-performance specific capacitance for supercapacitors but also rationalize the effects of hydrothermal conditions on the specific capacitance via various characterizations. The activation process of hydrochar is also studied by comparing various activators and the activator/hydrochar ratios. The obtained materials possess a three-dimensional interconnected hierarchical structure with rational pore size distribution and a specific surface area reach up to 1504 m2 g-1. Then the corresponding supercapacitors achieve a large specific capacitance of 324 F g-1 as the current density is 0.5 A g-1. These supercapacitors acquire an outstanding cycling stability with 99.7% capacitance retention after 5000 cycles. The assembled symmetrical supercapacitors also show a high energy density of 17.9 W h kg-1 and can maintain at 5.6 W h kg-1 even at an ultra-high power density of 50,400 W kg-1.Blumea balsamifera oil loaded cellulose acetate nanofiber mats were prepared by electrospinning. The inclusion of blumea oil increased the nanofiber diameter. FTIR spectra confirm the addition of blumea oil in the nanofiber mats. The XRD pattern suggests that the inclusion of blumea oil has caused a misalignment in the polymer chains of the cellulose acetate. Thus, a decrease in the tensile strength was observed for the blumea oil loaded nanofibers. The increase in fiber diameter causes a reduction in the porosity of the nanofiber mats. The blumea oil loaded nanofiber mats showed antibacterial efficacy against Escherichia coli and Staphylococcus aureus. The blumea oil showed antioxidant abilities against the DPPH solution. MVTR of the neat and blumea oil loaded nanofiber mats was in the range of 2450-1750 g/m2/day, which is adequate for the transport of air and moisture from the wound surface. Blumea oil loaded mats showed good cell viability ~92% for NIH 3T3 cells in more extended periods of incubation. A biphasic release profile was obtained, and the release followed the first-order kinetics depending upon the highest value of the coefficient of correlation R 2 (88.6%).We synthesized Schiff base and its complexes derivatives of chitosan (CS) in order to develop antibiotic compounds based on functionalized-chitosan against gram-positive and gram-negative bacteria. IR, UV-Vis, AFM, SEM, Melting point, X-ray diffraction (XRD), elemental analysis, and 1H NMR techniques were employed to characterize the chemical structures and properties of these compounds. XRD, UV-Vis, and 1H NMR techniques confirmed the formation of Schiff base and its functionalized-chitosan to metals. Subsequently, our antibacterial studies revealed that antibacterial activities of [Zn(Schiff base)(CS)] against S. aureus bacteria increased compared to those of their compounds. In addition, hemolysis test of CS-Schiff base-Cu(II) demonstrated better hemolytic activity than vitamin C, CS-Schiff base, CS-Schiff base-Zn(II), and CS-Schiff base-Ni(II). In a computational strategy, we carried out the optimization of compounds with molecular mechanics (MM+), Semi-emprical (AM1), Abinitio (STO-3G), AMBER, BIO+(CHARMM), and OPLS. Frontier orbital density distributions (HOMO and LUMO), and the optimized computational UV of the compounds were assessed. The optimized computational UV-Vis was similar to the experimental UV-Vis. We applied the docking methods to predict the DNA binding affinity, Staphylococcus aureus enoyl-acyl carrier protein reductase (ENRs), and Staphylococcus aureus enoyl-acyl carrier protein reductase (saFabI). Ultimately, the obtained data herein suggested that Schiff base is more selective toward ENRs and saFabI compared to chitosan, its complexes, and metronidazole.While ionic liquids (ILs) have been considered as effective and "green" solvents for biopolymer processing, regeneration of IL-dissolved biopolymers could largely impact biopolymer structure and properties. This study indicates that the reconstitution of chitosan structure during regeneration from 1-ethyl-3-methylimidazolium acetate ([Emim][OAc]) depends on anti-solvent (water, methanol or ethanol) largely. https://www.selleckchem.com/products/lotiglipron.html Irrespective of anti-solvent, the chitosan chemical structure was not varied by dissolution or regeneration. With water, the regenerated chitosan had the highest crystallinity index of 54.18%, followed by those with methanol (35.07%) and ethanol (25.65%). Water as an anti-solvent could promote chitosan chain rearrangement, leading to the formation of an ordered aggregated structure and crystallites. Density functional theory (DFT) simulation indicates that the number of hydrogen bonds formed between anti-solvents and [Emim][OAc] was in the order of water > methanol > ethanol. With water used for regeneration, the aggregation and rearrangement of chitosan chains occurred more easily.Glycosylation possess prominent biological and pharmacological significance in natural product and drug candidate synthesis. The glycosyltransferase YjiC, discovered from Bacillus subtilis (Bs-YjiC), shows potential applications in drug development due to its wide substrate spectrums. In order to elucidate its catalytic mechanism, we solved the crystal structure of Bs-YjiC, demonstrating that Bs-YjiC adopts a typical GT-B fold consisting of a flexible N-domain and a relatively rigid C-domain. Structural analysis coupled with site-directed mutagenesis studies revealed that site Ser277 was critical for Nucleoside Diphosphate (NDP) recognition, while Glu317, Gln318, Ser128 and Ser129 were crucial for glycosyl moiety recognition. Our results illustrate the structural basis for acceptor promiscuity in Bs-YjiC and provide a starting point for further protein engineering of Bs-YjiC in industrial and pharmaceutical applications.The object of this study was to utilize agro-industrial waste Corchorus olitorius stems (molokhia stems, MS) as substrate, for Aspergillus niger MK981235 xylanase production and as source of biologically active xylooligosaccharides (XOS). This study succeeded in utilization of Aspergillus niger MK981235 xylanase under different saccharification conditions designed by central composite design (CCD) for extraction of 15 biologically active XOS (anti-hepatotoxic, antioxidant, hypocholesterolemic and prebiotic) with different monosaccharides constituents composition and percent. A. niger MK981235 xylanase showed the highest activity 6.60 U·ml-1 at 50 °C with 1.5% xylan. The kinetics included Km and Vmax were determined to be 6.67 mg·ml-1 and 20 μmol·ml-1·min-1, respectively. Moreover, A. niger MK981235 xylanase thermodynamics Ea (activation energy) and Ed (activation energy of denaturation) were determined to be 21.95 and 39.51 KJ·mol-1, respectively. The highest prebiotic effect (growth promation) was exerted by the central MS XOS on Lactobacillus plantarum and Lactobacillus rhamnosus (125 and 135.
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