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https://www.selleckchem.com/ALK.html The use of a squaramide-based ion pair receptor offers a solution to the very challenging problem of extraction and transport of extremely hydrated sulfate salt. Herein we demonstrate for the first time that a neutral receptor is able not only to selectively extract but also to transport sulfates in the form of an alkali metal salt across membranes and to do so in a cooperative manner while overcoming the Hofmeister bias. This was made possible by an enhancement in anion binding promoted by cation assistance and by diversifying the stoichiometry of receptor complexes with sulfates and other ions. The existence of a peculiar 41 complex of receptor 2 with sulfates in solution was confirmed by UV-vis and 1H NMR titration experiments, DOSY and DLS measurements, and supported by solid-state X-ray measurements. By varying the separation technique and experimental conditions, it was possible to switch the depletion of the aqueous layer into extremely hydrophilic or less lipophilic salts, thus obtaining the desired selectivity.Long-term thermal stability is one limiting factor that impedes the commercialization of the perovskite solar cell. Inspired by our prior results from machine learning, we discover that coating a thin layer of 4,4'-dibromotriphenylamine (DBTPA) on top of a CH3NH3PbI3 layer can improve the stability of resultant solar cells. The passivated devices kept 96% of the original power conversion efficiency for 1000 h at 85 °C in a N2 atmosphere without encapsulation. Near-ambient pressure X-ray photoelectron spectroscopy (XPS) was employed to investigate the evolution of the composition and evaluate thermal and moisture stability by in situ studies. A comparison between pristine MAPbI3 films and DBTPA-treated films shows that the DBTPA treatment suppresses the escape of iodide and methylamine up to 150 °C under 5 mbar humidity. Furthermore, we have used attenuated total reflection Fourier transform infrared and XPS to prob

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