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https://www.selleckchem.com/products/telratolimod.html Bonds result strong enough to yield a stable gel phase, but they are still weak enough to allow network restructuring under thermal fluctuations.To advance the development of atomically precise Ag and Ag-alloyed nanoclusters, it is critical to develop effective synthetic methods. Herein, we successfully extend the CTAB (cetyl trimethyl ammonium bromide) reverse micelle method to synthesize a high-purity Ag44(p-MBA)30 (p-MBA = para-mercaptobenzoic acid) nanocluster and its corresponding alloy cluster Au12Ag32(p-MBA)30 in a short time (15 min and 5 min), with a high yield of ∼83% and ∼85%, respectively. Furthermore, the mechanism regarding the reverse micelle method has been clearly elucidated. Through characterizing the reaction system by Raman spectroscopy and NMR spectroscopy techniques, it can be revealed that employing CTAB to form reverse micelles to construct a sealed chemical environment is critical for realizing the fast and high-yield synthesis.The reaction of the dilithium diamido-diphosphine macrocycle, Li2[N(SiMe2CH2P(Ph)CH2SiMe2)2N] (Li2[P2N2]) with [Rh(COD)Cl]2 generates the dirhodium macrocyclic compound, [P2N2][Rh(COD)]2 (where COD = η4-1,5-cyclooctadiene), wherein both rhodium-COD units are syn to each other and have square planar geometries. While this dirhodium derivative does react with H2, no clean products could be isolated. Upon reaction of Li2[P2N2] with [Rh(COE)2Cl]2 (where COE is η2-cyclooctene), the dilithium-dihodium derivative ([Rh(COE)][P2N2]Li)2(dioxane) forms, which was characterized by single-crystal X-ray analysis and NMR spectroscopy. The cyclooctene derivative reacts with dihydrogen in benzene to generate the dilithium-dirhodium-dihydride complex ([Rh(H)2][P2N2]Li)2(dioxane); also formed is the dilithium-dirhodium-phenylhydride complex ([Rh(C6H5)H][P2N2]Li)2(dioxane) via oxidative addition of a C-H bond of the solvent. The phenyl-hydride is eventually converted to the dihydride

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