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https://www.selleckchem.com/products/dmog.html Lowering the energy barrier of water dissociation is critical to achieving highly efficient hydrogen evolution in alkaline conditions. Herein, we reported mesoporous RhRu nanosponges with enhanced water dissociation behavior as a new class of high-performance electrocatalysts for alkaline hydrogen evolution reaction (HER). The obtained nanosponges have a binary alloy structure (fcc) and a highly porous structure with high surface area. Our RhRu catalyst displayed an outstanding HER activity with an overpotential of 25 mV at 10 mA cm-2 and a Tafel slope of 47.5 mV dec-1 in 1.0 M KOH, which significantly outperformed that of commercial Pt/C catalyst and was even comparable to the classic Pt/metal (hydro)oxide catalysts. Density functional theory (DFT) calculations disclosed that charge redistribution on the RhRu alloy surface enabled tuning of the Ru d-band center and then promoted the adsorption and dissociation of water molecules. Based on the experimental results and theoretical modeling, a bifunctional mechanism contributed to the remarkable alkaline HER activity on the RhRu catalyst surface.A multi-functional polymer with aggregation-induced emission (AIE)-active salicylaldehyde azine (SA) functionality and reactive oxygen species (ROS)-responsive thioether groups is readily prepared via thiol-ene click polymerization of SA derivative diacrylate monomer, poly(ethylene glycol) diacrylate, and 3,6-dioxa-1,8-octanedithiol. The obtained AIE-active polymer exhibited an unexpected strong emission in amide solvents compared to that in other common organic solvents that was dramatically decreased by adding a trace amount of water, suggesting that the polymer could be utilized as a water trace indicator in amide solvents. In the backbone, the PEG segments make the polymer well dispersed in water and the ROS-responsive thioether groups enable this polymer as a promising ROS scavenger, with embedded SA moieties as a fluorescent

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