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https://www.selleckchem.com/products/ml349.html Sewerage sludge-derived biochars (SSDBCs) with high adsorption capacity and excellent recyclability were synthesized to remove tetrabromobisphenol A (TBBPA) in aqueous system. Scanning electron microscopy, elemental mapping via energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy were used to characterize the morphology, composition, and microstructures. The maximum adsorption capacity of SSDBCs was about 87.02 mg g-1 at 303 K and pH 7.5. The Langmuir isotherm demonstrated that the adsorption was mainly homogeneous and chemical processes. The kinetics of TBBPA removal well fitted the second-order dynamic model. Thermodynamic analysis showed that the adsorption was exothermic. The effect of π-π dispersive force and hydrogen bonding was proven as the main adsorption mechanism. Multiple cycle runs experiment revealed the excellent stability of recycled SSDBCs. This work provided a promising method of sludge resourceful treatment using an efficient, economic, cyclic, and convenient material for typical organic contaminant in the environment. This study assessed the quality of vegetation cover in the Parque Estadual das Várzeas do Rio Ivinhema (PEVRI, Upper Paraná River basin, MS, Brazil), the concentration of metals (Cd, Pb, Cr, Cu, Fe, Zn and Ni) in water and muscle and hepatic tissues of five fish species collected in the PEVRI - Hemiodus orthonops, Leporinus friderici, Prochilodus lineatus, Pterodoras granulosus and Pimelodus maculatus - in addition to non-carcinogenic risk assessment and genotoxicity potential in these species. Regarding vegetation index, we found that only 26.25% of the PEVRI area is occupied by denser vegetation. In the sites analyzed, Cd, Cu, Fe and Ni showed high concentrations in water, above the reference values established by the legislation. In the muscle and hepatic tissues of the fish species analyzed, Cd and Pb values exceeded th
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