Therefore, it was instructive to inhibit the formation of highly toxic intermediates in the photodegradation of environmental contaminants by regulating the ROS generated on the surface of the photocatalysts.The complexation of humic acid (HA) with dissolved Fe ions is beneficial to 2,4-dinitrotoluene degradation by PS/Fe2+, while the mechanism on HA binding with Fe ions is still unclear and warrants further exploration. In this study, the binding characteristics of HA with Fe ions and structural variations of HA during the complexation with Fe ions were investigated. Synchronous fluorescence analysis showed that the complexation ability of HA with Fe species at acid (pH = 5.0) and neutral condition (pH = 7.0) is higher than that of alkaline condition (pH = 9.0 and 11.0). Different components in HA including humic-like fraction (C1), fulvic-like fraction (C2), protein-like fraction (C3), and microbial-derived humic-like fraction (C4) were identified by excitation emission matrix-parallel factor analysis (EEM-PARAFAC). The complexation ability of C1, C2, and C4 with Fe species is higher than that of C3, and C1 and C4 primarily contributed to the complexation of HA with Fe species. Moreover, the sequence of HA structural variation during the complexation with Fe species was elucidated by Fourier transform infrared spectroscopy coupled with two-dimensional correlation spectroscopy analysis (2D FTIR COS), and could be concluded as follows ester→ quinoid rings→ aromatic groups→ aliphatic groups→ phenolic groups.Herein, FeCuMg and CrCuMg layered double hydroxides (LDHs) were synthesized and their sonophotocatalytic activities toward Acid blue 113 (AB113) were compared. Sonolysis alone (only ultrasound) led to the decolorization efficiency of 13.0 %. A similar result was obtained in the case of the utilization of photolysis alone using a 10-W LED lamp (13.5 %). The adsorption process of AB113 onto both compounds was not efficient to significantly remove the target contaminant. The bandgap energy of 2.54 eV and 2.41 eV was calculated for FeCuMg and CrCuMg LDHs, respectively, indicating relatively higher photocatalytic activity of Cr-incorporated LDH than FeCuMg LDH. The sonophotocatalysis of AB113 (50 mg L-1) over CrCuMg LDH (81.1 %) was more efficient than that of FeCuMg LDH (57.3 %) within the reaction time of 60 min. Intermediate byproducts of the sonophotocatalytic decomposition of organic dye over the as-synthesized tri-metal layered sonophotocatalysts were also identified. Furthermore, the antibacterial activity of both LDHs was evaluated by the CFU technique and the MBC and MIC values were determined. The antibacterial assessment confirmed the higher antibacterial activity of CrCuMg LDH than that of FeCuMg LDH against Staphylococcus aureus (S. aureus).The potential environmental pollution of chrome tanned leather results in the development of ecological chromium-free leather tanning production in leather industry. However, with weakly positive charge, chromium-free tanned leather cannot strongly bind to anionic dyes, thus causing low quality of finished leather. Herein, p(DM-co-[DDVIM]Br)PS was synthesized by free radical polymerization method. The structure and properties of the targeted products were synthetically characterized. The results indicated that the use of p(DM-co-[DDVIM]Br)PS fatliquoring agent can not only make leather fibers become loose, but also improve the binding affinity between leather and anionic dye during the fatliquoring process.  https://www.selleckchem.com/products/dbet6.html  The fatliquoring agent adsorption rates and the dye absorption rate of the leather were as high as 99.26% and 99.01%, respectively; the fatliquoring and dye solutions were clear, so they can be used as clean materials in the fatliquoring process of chromium-free tanned leather. Leather treated with p(DM-co-[DDVIM]Br)PS fatliquoring agent had higher K/S value (12.80) and is softer than those treated with commercial fatliquoring agent. Consequently, this study can not only help improve the absorption rate of anionic wet finishing materials, but also reduce the pollution caused by chrome tanning agents, thus providing a new way for the cleaner production in leather industry.Three-dimensional graphene-like biochar derived from Enteromorpha (EGB) was prepared as a persulfate (PS) activator for sulfamethoxazole (SMX) degradation. The graphitic N in the EGB samples not only endowed the superior binding energy towards SMX adsorption, but also promote the PS binding with the EGB, which was crucial to the catalytic degradation of SMX in EGB/PS system. Different from the radical-based oxidation in biochar prepared at 400 °C via the persistent free radicals (PFRs), both 1O2 and surface electron transfer served as non-radical pathways in the EGB samples prepared above 500 °C, acting together with free radicals (O2∙-) on SMX degradation. Oxidation of SMX and its substructural analogues indicated that the selective oxidizing reaction occurred in the EGB/PS system and the isoxazole ring in SMX molecule was insensitive to be attacked 1O2. In addition, toxicity predication indicated that the overall biotoxicity of the intermediates during SMX degradation was decreased.Characterization of antioxidant response is essential to elucidate the mechanism for plants tolerating arsenic (As) stress. Ten-day old lettuces were exposed to 50, 100, and 200 μg L-1 of arsenite (As(III)), arsenate (As(V)) or dimethylarsinic acid (DMA) for 50 days in hydroponic culture. The activities of superoxide dismutase, catalase, peroxidase, glutathione peroxidase, monodehydroascorbate reductase, dehydroascorbate reductase and glutathione reductase, as well as the glutathione concentration in tissues, were monitored. And the speciation and occurrence of As were concurrently analyzed in roots and leaves. The results showed that As(III) was the predominant As species in lettuces upon inorganic As exposure, while DMA was the primary As species upon DMA exposure. DMA presented higher mobility than inorganic As. The reduction of As(V) in roots upon As(V) exposure and in leaves upon As(III) exposure were suggested. The alterations of enzymatic antioxidant activities and non-enzymatic antioxidant contents showed that the antioxidant responses were As species-dependent, dose-dependent and tissue-dependent.