In this study, cadmium, copper, nickel, zinc, chromium, manganese and lead were determined in Cladophora fracta present in Lake Hazar (Turkey). The health risks (non-carcinogenic and carcinogenic) of heavy metals associated with the use of Cladophora fracta as mulch were also determined. Bioconcentration factor (BCF) and metal pollution index (MPI) were calculated. When compared with reference value (1.5 mg/kg for Cr and 200 mg/kg for Mn), the highest accumulation by Cladophora fracta was seen in the month of June as 1442 ± 7.2% (23.13 mg/kg) for Cr and the lowest accumulation calculated in the month of July as 5 ± 0.2% (210 mg/kg) for Mn. In our study, the highest MPI value was 13.69 in September. The magnitude of MPI values of heavy metals determined during April to September appeared in the following order September > August > July > June > May > April. The HQing (hazard quotient due to ingestion) and HQinh (hazard quotient due to inhalation) in all months were chidren > female > male while the order of HQder (hazard quotient due to dermal) was determined as male > female > children. Non-carcinogenic risk (HQ) and Hazard Index (HI) values in terms of ingestion, inhalation and dermal ways were lower than 1. Also, total HI values were  less then  1. As a result, there was not non-carcinogenic and carcinogenic risks associated with usage of Cladophora fracta as mulch.Severe tropospheric O3 pollution has swept across China in recent years.  https://www.selleckchem.com/products/plx5622.html  Consequently, investigation of tropospheric O3 concentration influencing mechanism is of significance for O3 pollution control in China. Previous studies have rarely detected combined impacts of natural factors and anthropogenic activities behind tropospheric O3 concentration in China at a national scale. Moreover, there is significant spatiotemporal heterogeneity of O3 pollution distribution in China due to the temporal and regional differences of socioeconomic and natural environmental condition in the vast territory. The targeted O3 control recommendations for different regions and seasons should be put forward in terms of the spatiotemporal heterogeneity of O3 concentration determinants. In this context, a three-level regression model integrating multi-scale biophysical and socioeconomic variables was proposed to explore the determinants of O3 pollution in China. The results showed that the tropospheric O3 concentration in the eastern and southeastern regions of China was strongly affected by meteorological conditions. In contrast, tropospheric O3 pollution concentrated in inland areas mainly depended on the emission intensity from anthropogenic sources.Many previous studies have investigated BTEX concentrations in urban areas; however, the available evidence on the association of different land-use types and BTEX concentrations is still scarce. In this study, the BTEX concentrations were measured and compared in different land-use types and traffic volumes of Mashhad metropolis, Iran. Sampling was conducted in summer and winter of 2018 based on NIOSH 1501 method in six land-use types, including Residential, Commercial/official, Industrial, Greenspace, Transportation, and Tourism. The spatial autocorrelation model was used to investigate the emission pattern. The Monte Carlo simulation technique and sensitivity analysis were used to assess the health risk of exposure to BTEX compounds. The median [interquartile range (IQR)] of benzene, toluene, ethylbenzene m-xylene, o-xylene and total BTEX concentrations based on overall mean were 4 (2.23), 8.37 (4.48), 1.2 (1.46), 0.89 (2.59), 0.8 (1.73) and 17.7 (8.19) µg/m3, respectively. Benzene and toluene had clustered emission patterns (z-score > 1.96). Exposure to benzene in the study area had a carcinogenic risk for inhabitants. The concentration of BTEX compounds was significantly different based on land-use type. The maximum and minimum concentrations of BTEX were observed in Transportation and Greenspace land uses, respectively. The BTEX concentrations in summer were significantly higher than in winter, and traffic had a significant effect on BTEX concentrations. Overall, our results supported a significant relationship between land-use type and BTEX concentrations in the urban area. Moreover, ambient benzene concentration had a carcinogenic risk potential for inhabitants of study area.To evaluate the effects of gaseous pollutants (SO2, NO2) on non-accidental mortality of residents in Hefei city, we collected non-accidental deaths, air pollutants and meteorological data of Hefei city from 2014 to 2017. After controlling confounding factors with Poisson generalized additive model, we analyzed the relationship between air pollutants and non-accidental mortality and used subgroup analysis to identify susceptible groups. The number of non-accidental deaths during the study period was 42,116, with an average of 28.83 per day. The average concentrations of SO2 and NO2 were 16.08 μg/m3 and 39.10 μg/m3, respectively. In the single-pollutant model, every 10 μg/m3 increase in SO2 and NO2 concentrations was significantly associated with non-accidental mortality, and there was a significant lag effect. SO2 increased the risk of non-accidental death by 4.93% (95% CI 1.94% ~ 8.00%) at lag0-3. In addition, male, the elderly, non-elderly and low-education people were more susceptible (P  less then  0.05). NO2 increased the risk of non-accidental death by 2.11% (95% CI 1.18% ~ 3.05%) at lag0-1 and had an effect on all subgroups (P  less then  0.05). For every 10 μg/m3 increase in SO2 and NO2, the two-pollutant model showed that the risk of non-accidental death, respectively, increased by 3.34% (95% CI 0.29% ~ 6.50%) and 1.82% (95% CI 0.85% ~ 2.79%), suggesting that the effect was weakened. Our study suggested that SO2 and NO2 were associated with non-accidental mortality, and there were lag effects. Therefore, environmental management should be strengthened and health protection education should be carried out for different groups.In the present study, the biochar derived from sunflower husks was used as a mediator in the heterogeneous Fenton process. The physical and chemical characteristics were studied in terms of specific surface area, elemental contents, surface morphology, surface functional groups, thermal stability, and X-ray crystallography. The main aim was to evaluate the effectiveness of biochar in a heterogeneous Fenton process catalyzed by hematite toward the degradation of benzo[a]pyrene (BaP) in Haplic Chernozem. The Fenton-like reaction was performed at a pH of 7.8 without pH adjustment in chernozem soil. The effects of operating parameters, such as hematite dosage and H2O2 concentrations, were investigated with respect to the removal efficiency of BaP. The overall degradation of 65% was observed at the optimized conditions where 2 mg g-1 hematite and 1.25 M H2O2 corresponded to the H2O2 to Fe ratio of 221. Moreover, the biochar amendment showed an increment in the removal efficiency and promotion in the growth of spring barley (Hordeum sativum distichum).