https://www.selleckchem.com/products/sb-505124.html The catalytic reduction of p-nitrophenol (4-NP) to 4-aminopyridine (4-AP) over Au nanoparticles can be increased by light illumination. Whether this is caused by the plasmonic effect remains unclear. The present research carried out a careful examination of the effects of light illumination and temperature on the catalytic conversion of 4-NP to 4-AP over Au nanorods. It was seen that light illumination has no effect on the apparent activation energy; this indicates that the catalytic mechanism is unchanged and the activity increase cannot be attributed to the effect of hot electrons. Based on the simulation of finite-difference time domain, the theoretical analysis also showed that plasmonic heating cannot play a major role. Thermographic mapping showed that the temperature of water solutions shows an increase under light illumination. By taking this temperature increase into consideration, the light-induced increase of the 4-NP to 4-AP conversion can agree well with dark catalysis, which cannot be attributed to the plasmonic effects of the Au nanorods.Different metal ions were used to modify Hβ zeolite adsorbents by an impregnation method to remove organic chlorides from the model naphtha. The dechlorination performance of different ion-modified adsorbents was evaluated using a microcoulometer. The effects of calcination time and temperature, metal loading, adsorption time and temperature, and dosage of adsorbent were investigated by batch adsorption experiments. The modified adsorbents were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), NH3-temperature-programmed desorption (TPD), scanning electron microscopy (SEM), infrared spectroscopy of pyridine adsorption (Py-IR), and X-ray photoelectron spectroscopy (XPS). After modification, the modified Zn/Hβ zeolite exhibited the best dechlorination performance among the other metal-loaded zeolites. The removal percentage of organic chloride of t