https://www.selleckchem.com/ATM.html Copper(I) π-coordination compounds with allyl derivatives of azoles are an interesting subject of current research, but CuI π-complexes with other transition-metal ions incorporated in the structure have been virtually uninvestigated. The present work is directed toward the synthesis and structural characterization of the novel heterometallic CuI/FeII π-complex di-μ2-chlorido-12κ2Cl;23κ2Cl-tetrakis[μ2-5-(prop-2-en-1-ylsulfanyl)-1,3,4-thiadiazol-2-amine]-12κ2N4N3;1(η2),κN42κN3;23κ2N3N4;2κN33(η2),κN4-dicopper(I)iron(II) tetrachloridoferrate(II), [Cu2FeCl2(C5H7N3S2)4][FeCl4] (1). The structure of the 5-[(prop-2-en-1-yl)sulfanyl]-1,3,4-thiadiazol-2-amine (Pesta, C5H7N3S2) ligand is also presented. The cationic substructure in 1 consists of one FeII and two CuI ions bridged by two chloride ions along with two σ,σ- and two π,σ-coordinated ligands, whereas the anionic part is built of isolated tetrahedral [FeCl4]2- ions. π-Coordination of the Pesta allyl group to the CuI ions prevents agglomeration of the inorganic Cu-Cl-Fe-Cl-Cu part into infinate chains. An energy framework computational analysis was performed for Pesta.The syntheses of four new cadmium and zinc complexes with 1,1'-bis(phosphanyl)ferrocene ligands and their phosphine chalcogenide derivatives are reported. The complexes were characterized by elemental analyses and IR, 1H NMR, 31P NMR and electronic absorption spectroscopy. The crystal structures of dichlorido[1-diphenylphosphinoyl-1'-(di-tert-butylphosphanyl)ferrocene-κ2O,P]cadmium(II), [CdCl2(C17H14OP)(C13H22P)Fe] or CdCl2(κ2P,O-dppOdtbpf) (1), bis[μ-(tert-butyl)(1'-diphenylphosphinoylferrocen-1-yl)phosphinato-κ3O,O'O'']bis[chloridozinc(II)], [Zn2(C9H13O2P)(C17H14OP)Fe2Cl2] or [ZnOClκ2O,O'-Ph2POFcPO2(t-Bu)]2 (2), 1,1'-bis(di-tert-butylthiophosphinoyl)ferrocene, [Fe(C13H22PS)2] or dtbpfS2 (3), and [1,1'-bis(dicyclohexylphosphanyl)ferrocene-κ2P,P'][chlorido/cyanido(0.25/1.75)]zinc(II), [Zn(CN)1.75Cl0.25(C17H26P)2Fe] or