Metal-stabilized radicals have been increasingly exploited in modern organic synthesis. Here, we theoretically designed a metalloradical complex Co-C˙Ph3 with the triplet characters through the transition metal cobalt (Co0) coordinating a triphenylmethyl radical. The potential catalytic role of this novel metalloradical in the CO2 reduction with H2/CH4 in the gas phase was explored via density functional theory (DFT) calculations. For the CO2 reduction reaction with H2, there are two possible pathways one (path A) is the activation of CO2 by Co-C˙Ph3, followed by the hydrogenation of CO2. The other (path B) starts from the splitting of the H-H bond by Co-C˙Ph3, leading to the transition-metal hydride complex CoH-H, which can reduce CO2. DFT computations show that path B is more favorable than path A as their rate-determining free energy barriers are 18.3 and 27.2 kcal mol-1, respectively. However, for the reduction of CO2 by CH4 two different products, CH3COOH and HCOOCH3, can be generated following different reaction routes. Both routes begin with one CH4 molecule approaching the metalloradical Co-C˙Ph3 to form the intermediate CoH-CH3. This intermediate can evolve following two different pathways, depending on whether the H bonded to Co is transferred to the O (pathway PO) or the C (pathway PC) of CO2. Comparing their rate-determining steps, we identified that the PO route is more favorable for the reduction of CO2 by CH4 to CH3COOH with the reaction barrier 24.5 kcal mol-1. Thus, the present Co0-based metalloradical system represents a viable catalytic protocol that can contribute to the effective utilization of small molecules (H2 and CH4) to reduce CO2, and provides an alternative strategy for the exploration of CO2 conversion.Charge injection from the near-by-electrode can occur during ferroelectric switching in the ferroelectric-dielectric bilayer due to the high field applied to the adjacent dielectric layers. The aim of this study is to investigate the effect of the charge injection by separating the amount of switched polarization and the injected charge density. A dynamic model of the injection-involved switching is developed and exploited to elucidate the mechanism. The model demonstrates that the amount of injected charges, which compensates for the bound charge of the polarization, can be larger, smaller, or identical to that of the polarization. This model further describes the analytical conditions of this compensation state. The model predictions are validated by the newly introduced ramping pulse measurements involving the serially connected TiN/Hf0.5Zr0.5O2/TiN and TiN/amorphous Al2O3/TiN, which are capable of separating the injected charge from the switched polarization. The dynamic model, along with the electrical measurements, enables the quantitative prediction and estimation of the internal potential and the effective charge, which is the sum of the bound and injected charges in the bilayer. This work provides fundamental insights into field-effect devices such as the next-generation ferroelectric-field-effect-transistors with NAND architecture based on uncompensated ferroelectric charges.A supramolecular strategy for detecting the concentration of polyamines has been established through competitive/synergetic complexation among polyamines, CB[7], γ-CD, and pyrene derivatives, which allows for convenient, rapid, and high throughput spectral/visual detection of the concentration of urinary polyamines based on the switching on/off of the pyrene excimer fluorescence.Electrochemical determination of histamine (HA) is quite challenging owing to the high oxidation potential and electrode fouling from HA oxide polyhistamine, which leads to poor sensitivity and unrepeatable measurement. In the present work, a simple, sensitive and repeatable electrochemical measurement of HA was developed based on a Nafion and multi-walled carbon nanotube (MWCNTs) composite membrane modified glassy carbon electrode (GCE). Compared with the bare GCE, the Nafion and MWCNT composite membrane modified electrode significantly enhanced the oxidation peak current and reduced the peak potential to 1.12 V (vs. SCE). Moreover, the characterization of the modified electrode by XPS and EIS showed that polyhistamine scarcely deposited on the composite membrane of the modified GCE, which made it possible to realize repeatable electrochemical measurement of HA.  https://www.selleckchem.com/products/ziritaxestat.html  The electrochemical oxidation behavior of HA on the modified electrode was studied by differential pulse voltammetry (DPV). The oxidation peak current has linear and natural log-linear relationships with HA concentration in the range of 20-200 μmol L-1 and 0.5-10 μmol L-1, respectively. The detection limit was 0.39 μmol L-1 (S/N = 3). The modified electrode could be used to determine 100 μmol L-1 HA ten times repeatedly; the peak currents in consecutive runs were all above 95% of the initial response. This method was also successfully applied to the determination of HA in fish samples and recoveries ranged from 98.2 to 101.2%.Correction for 'ZIF-8-modified Au-Ag/Si nanoporous pillar array for active capture and ultrasensitive SERS-based detection of pentachlorophenol' by Lingling Yan et al., Anal. Methods, 2020, 12, 4064-4071, DOI 10.1039/D0AY00388C.In this work a methodology to perform Bayesian model-comparison is developed and exemplified in the analysis of nuclear magnetic relaxation dispersion (NMRD) experiments of water in a ganglioside micelle system. NMRD is a powerful tool to probe slow dynamics in complex liquids. There are many interesting systems that can be studied with NMRD, such as ionic and lyotropic liquids or electrolytes. However, to progress in the understanding of the studied systems, relatively detailed theoretical NMRD-models are required. To improve the models, they need to be carefully compared, in addition to physico-chemical considerations of molecular and spin dynamics. The comparison is performed by computing the Bayesian evidence in terms of a thermodynamic integral solved with Markov chain Monte Carlo. The result leads to a conclusion of two micelle water-pools, and rules out both less and more parameters, i.e., one and three pools. On the other hand, if only the quality of the fits is considered (i.e., mean square deviation or χ2) a three water-pool model is the best.