Co-occurrence of arsenic and anions in groundwater causes a severe health problems and combine effects of these pollutants significantly affect performance of treatment process. Thus, this study has been conducted to examine the combine effects of anions on arsenic removal using aerated electrocoagulation (EC) reactor with 3D Al electrodes in groundwater. A 3-level, six factors Box-Behnken experimental design (BBD) was applied to investigate the individual and combine effect of anions and operating time phosphate (x1 1-10 mg L-1), silica (x2 20-80 mg L-1), bicarbonate (x3 130-670 mg L-1), fluoride (x4 2-10 mg L-1), boron (x5 5-10 mg L-1), and operating time (x6 8-22 min) on desired responses. The specified responses were effluent arsenic concentration (Cf,As), removal efficiency of arsenic (Re), consumptions of energy and electrode (ENC and ELC), operational cost (OC), and adsorption capacity (qe). The optimum operating parameters predicted using BBD were found to be x1 1.0 mg L-1, x2 26.0 mg L-1, x3 651.5 mg L-1, x4 2.0 mg L-1, x5 9.9 mg L-1, and x6 10.5 min considering highest removal efficiency of arsenic and lowest operational cost. Under these operating conditions, the experimental values of Cf,As, Re, ENC, ELC, OC, and qe were found to be 2.82 μg L-1, 98.6%, 0.411 kWh m-3, 0.0124 kg m-3, 0.098 $ m-3, and 17.65 μg As (mg Al)-1, respectively. Furthermore, mathematical modelling was conducted using quadratic regression model and response surface analysis was performed to understand the relationship between independent parameters and responses.The primary objective of the article was to establish the location of odour emitters with the use of spatial GIS analyses. The odour emitter location analysis based on measurements was carried out using QGIS software tools. https://www.selleckchem.com/Bcl-2.html The algorithm of the procedure was developed by analysing vector elements, including simulated odour streaks (in the form of wedge buffer surfaces) and a regular grid of points needed to determine the presence of a given buffer in a given location. Statistical analysis was performed in ArcGIS software. The detailed aim of the conducted study was to analyse the nuisance of odours from the measurement data on the basis of IDW interpolation and the arrangement of buildings. An innovative element of the developed analysis is the application of the inversed method of fragrance streak propagation. Identifying a streak from the measuring point towards the blowing wind is very likely to determine the approximate location of the odour emitter measured. The described method should provide better results at the location of emitters than the above mentioned methods using interpolation, because of taking into account wind direction and speed. In addition, it is a method that can be applied over a large open area where methods based on simulation and particle propagation would not be efficient or highly impossible to apply due to extensive and complex analysis. It was necessary to conduct field studies in order to meet the main goal, which resulted in sensory evaluation of the intensity of odour nuisance in an urbanised area. Odour concentration tests using field olfactometry with NasalRanger olfactometer were taken.Vitellogenin (VTG) is typically produced by females but when present in males can indicate contamination with estrogenic endocrine-disrupting chemicals (EDCs). Here we used primary hepatocytes isolated from male crucian carp uncontaminated with estrogenic EDCs as a culture model. Nine EDCs were used for validation, and an enzyme-linked immunosorbent assay (ELISA) was used to quantify VTG production by primary hepatocytes. The lower limit of detection of 17β-E2, DES, and HES using the method was 10-12 M. Fresh pork was roasted, and non-hydrolytic acetonitrile-vortexing was used to extract potential estrogenic EDCs. The extracted substances were separated by thin-layer chromatography (TLC), and dimethyl terephthalate present in roast pork was found to induce high VTG concentrations. Therefore, the detection of VTG by ELISA provides a sensitive and reliable method for detecting known and unknown estrogenic EDCs in food products.Copper(II) phthalocyanine (CuPc) and non-peripheral octamethyl-substituted copper(II) phthalocyanine (N-CuMe2Pc) were combined with reduced graphene oxide (rGO) via a precipitation method to form CuPc/rGO and N-CuMe2Pc/rGO nanocomposites, respectively. CuPc nanorods are distributed on rGO, and N-CuMe2Pc exists as nanorods and nanoparticles on rGO. The Cr(VI) removal ratio of N-CuMe2Pc/rGO exposed in simulated sunlight is 99.0% with a fast photocatalytic reaction rate of 0.0320 min-1, which is approximately 1.5 times faster than that of CuPc/rGO (0.0215 min-1) and far surpasses that of pristine phthalocyanine and rGO. As an electron acceptor, rGO can suppress the recombination of photo-induced electron-hole pairs and also can provide a large surface area for Cr(VI) removal, both of which are beneficial to the reducing capacity of the nanocomposites. The higher removal efficiency of N-CuMe2Pc/rGO compared with that of CuPc/rGO is attributed to the higher specific surface area, higher light harvesting, higher conductivity and more negative lowest unoccupied molecular orbital level of N-CuMe2Pc/rGO. The N-CuMe2Pc/rGO nanocomposite shows excellent photochemical recyclability which is essential for application in wastewater treatment.Prenatal exposure to persistent organic pollutants (POPs) has been a matter of particular concern because such exposure can severely affect the health of the fetus. The mechanistic understanding of the partitioning behavior of POPs in the feto-maternal system and the associated factors, however, have rarely been studied. Here, we employed a new approach based on multiple linear regression (MLR) analysis to predict the feto-maternal ratio (FM-ratio) of POPs and to assess the factors associated with feto-maternal partitioning behavior. Two preliminary exploratory MLR models were built using physiological conditions of the participants, and molecular descriptors were calculated with a computational model. The FM-ratio was calculated from the concentrations of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs), and polybrominated diphenyl ethers (PBDEs) in 20 pairs of maternal and cord blood. The models showed that the lipids and cholesterols in the maternal and cord blood and the placenta significantly influence the partitioning of POPs.