Denitrification is an important process affecting nitrogen dynamics in soils. In this study, abundances of denitrification genes (narG, nirK, nirS, and nosZ) and activities of nitrite reductase (S-NiR), nitrate reductase (S-NR) were measured in heavy-metal polluted soils with different amendments of biochar and compost. The relationships between physical-chemical parameters, denitrification gene abundance, and enzyme activity were analyzed by Pearson correlation method. Results showed that compost addition significantly increased the abundances of functional genes (nirS, nosZ, narG), and the abundances of nirK and nirS might be sensitive to compost and biochar addition. Compost addition and its combination with biochar significantly decreased the S-NiR enzyme activity and stimulated the S-NR enzyme activity. Negative relationships were obtained between S-NiR activity and electric conductivity (EC), water soluble carbon (WSC), nitrate, ammonium, nirK, narG gene abundances. While S-NR activity significantly positively correlated with soil EC, WSC and nirK gene abundance. Biochar and compost amendments can alter soil nitrogen cycling by changing denitrifying functional gene and relevant enzyme activities in soils polluted by heavy metals.Crayfish, an aquatic food consumed globally, has been reported to accumulate heavy metal. To assess the health risk to the crayfish-consuming population, we investigated heavy metals (Cu, Pb, Zn, Fe, Mn, Cd, Cr, Ba, and As) in crayfish tissues (exoskeleton, abdominal muscle, gills, and hepatopancreas) and sediments from uncultivated and cultivated ponds in the middle reach of the Yangtze River. The metals, except for As, were measured by Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) and As was measured by atomic fluorescence spectrometry. The distribution of heavy metals differed significantly among tissues and concentrations were generally highest in the hepatopancreas. The average concentrations of heavy metals were higher in crayfish from uncultivated ponds than in crayfish from cultivated ponds. Heavy metal concentrations in crayfish correlated positively with sediment concentrations in uncultivated ponds, indicating that heavy metals can accumulate in crayfish. However, this positivesearch was designed to protect food safety and the results indicate that the health risk posed by heavy metals in crayfish is low.Electrospun nanofiber membranes (ENMs) have high porosity, high specific surface area and unique interconnected structure. It has huge advantages and potential in the treatment and recycling of wastewater. In addition, ENMs can be easily functionalized by combining multifunctional materials to achieve different water treatment effects. Based on this, this review summarizes the preparation of functionalized ENMs and its detailed application in the field of water treatment. First, the process and influence factors of electrospinning process are introduced. ENMs with high porosity, thin and small fiber diameter have better performance. Secondly, the modification methods of ENMs are analyzed. Pre-electrospinning and post-electrospinning modification technology can prepare specific functionalized ENMs. Subsequently, functionalized ENMs show water treatment capabilities such as separation, adsorption, photocatalysis, and antimicrobial. Subsequently, the application of functionalized ENMs in water treatment capabilities such as separation, adsorption, photocatalysis, and antimicrobial capabilities were listed.  https://www.selleckchem.com/products/pifithrin-alpha.html  Finally, we also made some predictions about the future development direction of ENMs in water treatment, and hope this article can provide some clues and guidance for the research of ENMs in water treatment.Urban trees provide important ecosystem services, including air quality improvement. Polycyclic aromatic hydrocarbons (PAHs) are among the most important pollutants in air, due to their elevated concentrations and toxicity. Plants can act as filters of PAHs and as "chemical reactors" for pollutant removal, therefore reducing air concentrations. Here, the first assessment of photo- vs. biodegradation of PAHs on leaves of urban trees is presented. A dynamic air-vegetation-soil model (SoilPlusVeg) was improved to simulate the fate of two representative PAHs with contrasting physico-chemical properties (phenanthrene and benzo[a]pyrene). Simulations were performed for two different environmental scenarios from Italy (Como and Naples), selected for their dissimilar meteorological parameters, plant species and emission levels. The effect of photo- and biodegradation on leaf concentrations and fluxes towards air and soil was investigated comparing deciduous (maple, cornel and hazelnut) and evergreen (holm oak) broadleaf woods. The results showed that biodegradation in the phyllosphere could not be neglected when evaluating the ecosystem services provided by urban trees, as this process contributed significantly to the reductions (up to 25% on average) in PAH leaf concentrations and fluxes to air and soil; however, the reductions revealed ample variations with time (up to more than two orders of magnitude) showing the dependence on meteorological parameters, air compartment structure, as well as type of woods. These findings permitted to improve the ecological realism of the simulations and obtain more accurate results when predicting organic contaminant uptake and release by plant leaves, including potential for food chain transfer and long-range transport.The effect of the nonsphericity of mineral dust aerosols on its deposition and transport was investigated based on model simulation for a typical dust event over northern China from April 6 to 12, 2018. The settling velocity related to morphological change in dust size was considered in Nested Air Quality Prediction Modeling System (NAQPMS) to simulate the dust spatial distribution. Comparison of these results with observations showed that the model reproduced the temporal variability in the mass concentration of particles along the dust plume pathway. The most frequently reported aspect ratio (λ) was 1.7 ± 0.2 for Asian dust aerosols. Changing the nonsphericity of the particle from typical prolate ellipsoids (λ = 1.7) to spherical ellipsoids (λ = 1) caused an ~3% decrease in the surface dust concentration on average. For particles with diameters >5 μm, nonsphericity caused a change in the surface dust concentration up to 10%, especially at the periphery of the dust source region. The overall effects on the fine dust ( less then 2.