Traditional Fenton or Fenton-like oxidation has been widely studied for waste activated sludge dewaterability. However, the narrow pH range (2.0-4.0) and the instabilities of Fe2+ and H2O2 have hindered its commercial application. Owing to the high alkalinity of anaerobic digestion (AD) sludge, traditional Fenton or Fenton-like oxidation is economically unfeasible for its dewatering. In this study, we successfully demonstrated a novel and feasible method that used nitrilotriacetic acid (NTA)-Fe0 combined with CaO2 (NTA-Fe0/CaO2) at near-neutral pH (∼6.0) (a slight pH adjustment) in which capillary suction time ratio (CST0/CST) and centrifuged weight reduction (CWR) improved by 6 folds and 42.98 ± 0.37%, respectively, under the optimal conditions. The presence of NTA accelerated the Fe0 corrosion, Fe2+ stability and turnover between Fe2+ and Fe3+. As such, Fe0 could effectively catalyze CaO2 to produce hydroxyl radicals (•OH) under near-neutral conditions. Accordingly, various molecular weight hydrophilic compounds in different extracellular polymeric substances fractions were significantly reduced after treatment. The hydrophilic functional groups especially protein molecules were largely reduced. Consequently, the viscosity of sludge and particle size effectively decreased, while the release of bound water, surface charge, flocculation, and flowability of sludge were improved. The cost-benefit analysis further demonstrated the NTA-Fe0/CaO2 treatment has high reusability and stability and is also more economical over the FeCl3/CaO and Fenton's reagent/CaO treatments. In summary, the NTA-Fe0/CaO2 process is a cost-effective and practically feasible technology for improving AD sludge dewaterability.Faced with the dual constraints of resources and the environment, green technology innovation has become an important measure to solve the development challenges of heavily polluting industries. From the perspective of institutional regulation theory, this paper studies the impact of direct environmental regulation on green technology innovation in Chinese listed companies of heavily polluting industries by using the Panel Poisson fixed effect model. Besides, the heterogeneity of ownership and industry is discussed. The results indicate that direct environmental regulations exert a strong and significant incentive effect on green technology innovations in heavily polluting industries.  https://www.selleckchem.com/products/Sunitinib-Malate-(Sutent).html  Regarding the heterogeneity of enterprise ownership, direct environmental regulations were found to be more significant to the green technology innovations of state-owned listed companies in such industries. Considering industry heterogeneity, compared with labor-resource intensive industries, direct environmental regulation can effectively encourage green technology innovations in technology-capital intensive industries. This study provides a policy basis for promoting environmental governance and green technology innovation in China's heavily polluting industries.Polycyclic aromatic hydrocarbons (PAHs) are global contaminants of concern. Despite several decades of research, their mechanisms of toxicity are not very well understood. Early life stages of fish are particularly sensitive with the developing cardiac tissue being a main target of PAHs toxicity. The mechanisms of cardiotoxicity of the three widespread model polycyclic aromatic hydrocarbons (PAHs) retene, pyrene and phenanthrene were explored in rainbow trout (Oncorhynchus mykiss) early life stages. Newly hatched larvae were exposed to sublethal doses of each individual PAH causing no detectable morphometric alterations. Changes in the cardiac proteome and metabolome were assessed after 7 or 14 days of exposure to each PAH. Phase I and II enzymes regulated by the aryl hydrocarbon receptor were significantly induced by all PAHs, with retene being the most potent compound. Retene significantly altered the level of several proteins involved in key cardiac functions such as muscle contraction, cellular tight junctions or calcium homeostasis. Those findings were quite consistent with previous reports regarding the effects of retene on the cardiac transcriptome. Significant changes in proteins linked to iron and heme metabolism were observed following exposure to pyrene. While phenanthrene also altered the levels of several proteins in the cardiac tissue, no clear mechanisms or pathways could be highlighted. Due to high variability between samples, very few significant changes were detected in the cardiac metabolome overall. Slight but significant changes were still observed for pyrene and phenanthrene, suggesting possible effects on several energetic or signaling pathways. This study shows that early exposure to different PAHs can alter the expression of key proteins involved in the cardiac function, which could potentially affect negatively the fitness of the larvae and later of the juvenile fish.In water-limited areas, revegetation of abandoned croplands may lead to extensive land-use changes and considerable variations on soil carbon (C) and nitrogen (N). However, the impact of land-use patterns (i.e., the spatial combinations of different land-use types) on soil C and N variations following revegetation remains unclear. In this study, we measured soil organic carbon (SOC), total carbon (TC), and total nitrogen (TN) stocks to a depth of 200 cm in grassland (GL), shrubland (SL), young forestland (YF), and mature forestland (MF) under four land-use patterns in a catchment located in the Chinese Loess Plateau. The highest SOC, TC and TN stocks occurred in MF and the lowest was found in GL. Compared to every single land-use type, soil C and N stocks significantly increased under different land-use patterns. The highest SOC stock (6.51 kg m-2) was found in the GL-YF-SL pattern, and the highest TC stock (47.25 kg m-2) and TN stock (0.70 kg m-2) were both observed in the MF-YF pattern. SOC stocks showed significantly positive correlations with TC and TN stocks under different land-use patterns (p less then 0.05), except for the GL-MF. The soil C-N interactions were stronger in the MF-SL and GL-YF-SL patterns compared to the GL-MF and MF-SL. Redundancy analysis indicated that the SOC, TC, and TN variations were well explained by aboveground biomass and land-use patterns, with accumulated variance of 41.6% and 54.2% in Axis 1 and Axis 2, respectively. The differences of soil C and N accumulation among land-use patterns were mostly related to different vegetation coverage and the intensity of soil erosion. This study indicates that creating proper spatial distribution of land-use types on hillslopes could benefit soil C and N sequestrations and ecosystem restoration in semi-arid environments.