A wide variety of tumorigenic mechanisms involved in chronic Cd exposure and the beneficial effects of flavonoids against Cd-induced carcinogenicity necessitate further investigations.TiO2-supported antimony oxide-vanadium oxide-cerium oxide (SVC) imparts Lewis acidic (L)/Brönsted acidic (B) sites, labile (Oα)/mobile oxygens (OM), and oxygen vacancies (OV) for selective catalytic NOX reduction (SCR). However, these species are harmonious occasionally, readily poisoned by H2O/sulfur/phosphorus/carbon, thus limiting SCR performance of SVC. Herein, a synthetic means is reported for immobilizing HSOA-/SOA2- (A= 3-4) or H3-BPO4B- (B= 1-3) on the L sites of SVC to form SVC-S and SVC-P. HSOA-/SOA2-/H3-BPO4B- acted as additional B sites with distinct characteristics, altered the properties of Oα/OM/OV species, thereby affecting the SCR activities and performance of SVC-S and SVC-P. SVC-P activated Langmuir-Hinshelwood-typed SCR better than SVC-S, as demonstrated by a greater Oα-directed pre-factor and smaller binding energy between Oα and NO. Meanwhile, SVC-S provided a larger B-directed pre-factor, thereby outperforming SVC-P in activating Eley-Rideal-typed SCR that dictated the overall SCR activities. Compared with SVC-S, SVC-P contained fewer OV species, yet, had higher OM mobility, thus enhancing the overall redox cycling feature, while providing greater Brönsted acidity. Consequently, the resistance of SVC-P to H2O or soot were greater than or similar to that of SVC-S. Conversely, SVC-S revealed greater tolerance to hydro-thermal aging and SO2 than SVC-P. This study highlights the pros and cons of HSOA-/SOA2-/H3-BPO4B- functionalities in tailoring the properties of metal oxides in use as SCR catalysts.Recently, an increasing number of works have been reported about iron-based materials applied as catalysts in peroxide activation processes to degrade pollutants in water. Iron-based catalysts include synthetic and natural iron-based materials. However, some synthetic iron-based materials are difficult to scale up in the practical applications due to high cost and serious secondary environmental pollution. In contrast, natural iron-based minerals are more available and cheaper, and also hold a great promise in peroxide activation processes for pollutant degradation. In this review, we classify different natural iron-based materials into two categories iron oxide minerals (e.g., magnetite, hematite, and goethite,), and iron sulfide minerals (e.g., pyrite and pyrrhotite,). Their overview applications in peroxide activation processes for pollutant degradation in wastewaters are systematically summarized for the first time. Moreover, the peroxide activation mechanisms induced by natural minerals, and the influences of reaction conditions in different systems are discussed. Finally, the application prospects and existing drawbacks of natural iron-based minerals in the peroxide activation processes for wastewater treatment are proposed. We believe this review can shed light on the application of natural iron-based minerals in peroxide activation processes and present better perspectives for future researches.The unique properties of heterostructure materials make them become a promising candidate for high-performance room-temperature (RT) NO2 sensing.  https://www.selleckchem.com/products/Temsirolimus.html  Herein, a p-n heterojunction consisting of two-dimensional (2D) MoS2 nanoflakes vertically grown on one-dimensional (1D) SnO2 nanotubes (NTs) was fabricated via electrospinning and subsequent hydrothermal route. The sulfur edge active sites are fully exposed in the MoS2@SnO2 heterostructure due to the vertically oriented thin-layered morphology features. Moreover, the interface of p-n heterojunction provides an electronic transfer channel from SnO2 to MoS2, which enables MoS2 act as the generous electron donor involved in NO2 gas senor detection. As a result, the optimized MoS2@SnO2-2 heterostructure presents an impressive sensitivity and selectivity for NO2 gas detection at RT. The response value is 34.67 (Ra/Rg) to 100 ppm, which is 26.5 times to that of pure SnO2. It also exhibits a fast response and recovery time (2.2 s, 10.54 s), as well as a low detection limit (10 ppb) and as long as 20 weeks of stability. This simple fabrication of high-performance sensing materials may facilitate the large-scale production of RT NO2 gas sensors.Chloropicrin as one of the most frequently detected N-DBPs has drawn great attention due to its high toxicity. However, our understanding of its formation mechanism is still very limited. A combined computational and experimental approach was used in this study to reveal chloropicrin formation mechanism during chlorination. Ethylamine, n-propylamine, alanine and tryptophan along with the above two amines and their four derivatives substituted by -OH or/and -NO2 groups were chosen as computational and experimental model precursors, respectively. The results indicate that primary amines and free amino acids are more likely to share the same chloropicrin formation pathway including N-chlorination, imidization, β-C-alcoholization, N-nitration, α-C-chlorination and dealdehydation processes. Moreover, elimination of hydrochloric acid from N,N-dichloro-amine and electrophilic addition of N-chloroalkylimide with hypochlorous acid were found to be the rate-limiting steps among all the elementary reactions. By skipping over both of the above rate-limiting steps, RCH(OH)CH2NO2 and RCH(OH)CH2NH(OH) compounds were proposed to be potent chloropicrin precursors, and experiments confirmed that 2-nitroethanol and N-methylhydroxylamine have the highest chloropicrin yields in the chlorination among all the precursors reported to date. The findings of this work are helpful for expanding the knowledge of chloropicrin formation mechanisms and predicting the potential chloropicrin precursors.The treatment of cyanide wastewater from the gold industry is essential. Photocatalytic oxidation is an effective method for the elimination of cyanides and metal cyanide complexes. TiO2/ZSM-5 composite photocatalysts with different SiO2/Al2O3 ratios were prepared using the solid-state dispersion (SSD) method. The composite catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 adsorption-desorption, and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). The catalytic efficiency of different SiO2/Al2O3 ratios and the synergistic effect of adsorptive photocatalytic oxidation for the degradation of cyanide wastewater was investigated under different adsorption and illumination times. With the extension of the photocatalytic time (>2.0 h), the composite catalyst with a high SiO2/Al2O3 ratio had better photocatalytic performance. A 93.97% degradation efficiency of total cyanides was observed after adsorption for 3.0 h and illumination for 4.0 h under room temperature with air as the oxidant.