https://www.selleckchem.com/products/beta-glycerophosphate-sodium-salt-hydrate.html 7%). Future control strategies for the winter haze should also aim to lower photochemical oxidants, via larger and synchronized NOX and VOCs emissions reduction, to overcome the effects of nonlinear photochemistry and aerosol chemical feedback.Symmetrical and unsymmetrical chromophores of isoindigo 3-7 were designed and synthesized, in which isoindigo was used as the central unit (electron acceptor unit A), triphenylamine as the end capping unit (electron donor group D), 1,1,4,4-tetracyanobutadiene (TCBD, A') and cyclohexa-2,5-diene-1,4-diylidene-expanded TCBD (A″) as the acceptor unit. The effects of multiacceptor units on photophysical, electrochemical, and computational studies were investigated. The photophysical properties of isoindigo 6 and 7 exhibit a strong intramolecular charge transfer (ICT) absorption band in the near IR region. The isoindigo 4-7 shows multi-redox waves with a low electrochemical band gap, which signifies the tuning of highest occupied molecular orbital-lowest unoccupied molecular orbital energy levels and enhance the π-conjugation. The computational studies demonstrate that there is a good agreement with experimental data. The molecular design and synthesis of isoindigo 4-7 gives a new avenue for the development of building blocks in organic electronics.Advanced oxidation processes tend to have very complex reaction mechanisms, and models containing over 150 steps have been developed to describe the chemistry. Without the aid of automation, it is extremely difficult to avoid the development of kinetic mechanisms that violate the principle of detailed balancing. Here, we apply DETBAL, a computer application, to systematically identify many violations of the principle of detailed balancing in a model proposed for the UV/chloramine process. We then show that these violations can also be found in dozens of other proposed models for advanced oxidation processe