In particular, the new equation contributes to obtaining the PBDEs concentrations in all atmospheric phase from partial phase, then provides a credible path to evaluate healthy exposure dose from the airborne PBDEs, by co-utilization with exposure models.The stereoselective behaviors of triadimefon (TF) and its metabolite triadimenol (TN) during barley storage and beer brewing were studied by supercritical fluid chromatography-tandem mass spectrometry to shed light on potential security risks. Matrix-matched calibration curves were constructed for barley and beer, with determination coefficients (r2) ≥ 0.9991. Average recoveries of 77.2-107.5 % and relative standard deviations within 15.0 % were observed. The degradation of the TF enantiomers during storage followed pseudo-first-order kinetics, and S-TF was degraded in preference to R-TF with the half-life ranges 18.5-36.5 d and 20.4-69.3 d, respectively. During beer brewing, the TF enantiomers (enantiomer fraction, 0.44-0.56) were selectively metabolized into TN stereoisomers (diastereomer fraction, 0.43-0.58). The total pesticide content of beer was 93.3 % lower than that of raw grain, whereby the TF content declined by up to 100 % and the TN stereoisomers were reduced by 35.1 %. The processing factors of all the brewing steps were less than one, illustrating that beer consumption is safer after its commercial processing. Furthermore, the TF enantiomers showed different behaviors upon fermentation by two yeast strains. Thus, this work is a useful reference for assessing the food safety risk posed by individual pesticide enantiomers and their contribution to environmental pollution.Gold nanorods (AuNR) have been explored for many applications, including innovative nanomedicines, which also might contribute to its increase in the environment, namely due to inadequate disposable of wastes into aquatic environments. Early-life stages of amphibians are usually aquatic and sensitive to chemical contamination. Accordingly, this study aimed to determine the sublethal effects of CTAB functionalized AuNR on Xenopus laevis tadpoles. As such, tadpoles were exposed to serial concentrations of AuNR for 72 h. A reduction in the rate of feeding (EC50 = 4 μg.L-1), snout to vent growth (EC50 = 5 μg.L-1) and weight gain (EC50 = 6 μg.L-1), was observed for AuNR-exposed tadpoles. Also, tadpoles actively avoided concentrations ≥ 4 μg.L-1 of AuNR, after 12 h of exposure. At the biochemical level, AuNR caused impairments in antioxidant and nervous system related enzymes. Exposure to CTAB alone caused a high mortality. Results indicated that CTAB functionalized AuNR may induce several sublethal effects that may compromise the organism's fitness. Avoidance behavior (which corresponds to the disappearance of organisms, thus, similar to their death), observed at concentrations matching those inducing sublethal effects, suggest that it should be considered in the risk assessment for amphibians.Recycling of spent alkaline Zn-Mn batteries (S-AZMB) has always been a focus of attention in environmental and energy fields. However, the current research mostly concentrated in the recovery of purified materials, and ignores the direct reuse of S-AZMB. Herein, we propose a new concept for the first time that unpurified S-AZMB can be used as raw materials for preparation of Z-scheme photocatalytic system in combination with TiO2. A series of characterizations and experiments confirm that the combination with S-AZMB not only extends the response of TiO2 to visible light, but also significantly enhances the separation ability of photogenerated electron-hole pairs. In the toluene removal experiment, the degradation kinetic rate of Z-scheme TiO2@S-AZMB photocatalyst reaches 21.0 and 10.5 times than that of TiO2 and S-AZMB, respectively. More notably, this S-AZMB based Z-scheme photocatalyst can maintain structural and photocatalytic performance stability in cyclic catalytic reactions. We believe that this work not only expands the research concept of recycling S-AZMB, but also provides a new idea for designing highly efficient Z-scheme photocatalysts.The concentrations of 14 perfluoroalkyl substances (PFASs) and 46 pharmaceuticals in raw water and drinking water from five drinking water treatment plants were determined to assess removal of the chemicals during treatment. 10 out of 14 PFASs were detected in the raw and drinking water samples. The mean perfluorohexane sulfonate concentrations in raw and drinking water were the highest with levels of 106 and 69.6 ng L-1, respectively and the other PFAS concentrations were lower. The ∑14PFAS and individual PFAS removal efficiencies for the treatment plants were -36.9% to 70.7% (mean 31.3%) but the granular activated carbon process removed >80% of the total amount of long-chain PFASs that was removed.  https://www.selleckchem.com/products/sulbactam-pivoxil.html  The removal efficiency increased as the perfluorocarbon chain length increased. The removal efficiencies increased by 14.2% and 11.2% from the shortest to the longest perfluoroalkyl carboxylic acid and perfluoroalkyl sulfonic acid chain lengths, respectively. 20 out of 46 pharmaceuticals were detected in the raw water samples, but most were removed completely during treatment. Only caffeine, carbamazepine, crotamiton, fenbendazole, metformin, and sulfamethoxazole were detected in the drinking water samples. Oxidation processes contributed >90% of the overall treatment plant removal efficiency except for metformin.Atmospheric transport could be a significant pathway for inland microplastics (MPs, with size＜5 mm) to the ocean in addition to catchment runoff and coastal discharge. However, atmospheric input of MPs to the ocean is rarely quantified. To address this issue, transport of atmospheric MPs from source to sink was studied in the Asia-Pacific region during nine cruises from October 2018 to September 2019. Both deposited atmospheric MPs (DAMPs) and suspended atmospheric MPs (SAMPs) were collected, ranging from 23.04 n/(m2·d) to 67.54 n/(m2·d), and 0 to 1.37 n/m3, respectively. Size composition revealed that atmospheric deposition of MPs originating in terrestrial regions seems inadequate and insufficient to quantify the atmospheric input to the ocean. In addition, combined with aerodynamic modelling, for the first time, we estimated that 7.64-33.76 t of fibrous atmospheric MPs was globally generated in 2018, which is 3 % and 31 % of riverine input MPs of The Yangtze River and The Pearl River in terms of mid-point mass, respectively.