Toxic metals and metalloids (TMMs) in soil can be accumulated in crops, which poses potential risks to human health. In this paper, 55 topsoil and 23 crop samples, collected in Qilihe, China, were selected to study the contamination, risk, and plant accumulation of TMMs in soil-crop system. TMM concentrations in soil samples were all below the permissible limits, but Hg and Cd exhibited the potential ecological risk due to their slight accumulation in soil. There was slight Hg pollution in 2 samples of Lanzhou lily (Lilium davidii), and 1 sample of radish (Raphanus sativus), Chinese cabbage (Brassica pekinensis), and welsh onions (Allium fistulosum) due to Hg's strong bio-accumulation, but there was no risk to human health. The TMM accumulation in leaf crops was large, followed in tuber and seed crops. Available potassium, cation exchange capacity, soil organic matter, and available phosphate were the main factors associated with TMM accumulation in crops among the selected soil properties. This study shows the current contamination situation and the predominant influencing factors associated with the accumulation of TMMs in 24 crops, which provides the emphasis and direction of relative policies in land use and crop plantation.The photovoltaic (PV) for irrigation system is an emerging technology to harness the solar energy. The performance of the PV modules depends on the incident solar radiation, geographical location, and the surface temperature of the modules. The performance of the PV system needs to be monitored by manually or embedded controllers. The commercially available technologies for monitoring the system are costlier and need to be optimized. The Arduino controller is used to monitor the performance of the photovoltaic (PV) system in Coimbatore (11.016° N, 76.9558° E), Tamilnadu, India. The PV surface temperature is monitored and controlled by flowing the water above the module by setting the mean ambient temperature as a reference temperature 34 °C when the system exceeds the reference temperature. PV surface temperature is reduced up to 16°C thus improved the electrical efficiency by 17% compare to the reference module. The Arduino controller control the relay to switch on the motor to control the mass flow rate of the water at 0.0028kg/s. The various parameters are measured such as voltage, current, and solar radiation of the location and analyzed. The estimated cost of monitoring system and various sensor is 10$ which cost comparatively 50% lower than the other PV monitoring controllers. This method can be employed in the medium and large-scale irrigation system.As can be volatilized naturally; however, this has adverse environmental effects. In this study, we investigated As volatilization in flooded paddy soil with the addition of biochar (BC) and Fe-Mn-La-modified BC composites (FMLBCs). The addition of BC and FMLBCs caused decreases in total As volatilization in the soil over 7 weeks. Maximum volatilization was achieved in the third week followed by stabilization. Volatilization decreased by 21.9%, 18.8%, 20.8%, and 31.1% with the addition of BC, FMLBC1, FMLBC2, and FMLBC3 (BC/Fe/Mn/La weight ratios different), respectively, in lightly contaminated soil, and by 15.2%, 20.5%, 17.6%, and 25.4%, respectively, in highly contaminated soil. The FMLBCs decreased the exchangeable As fractions and increased the non-swappable As in the soil. Furthermore, the addition of FMLBCs significantly reduced the As(III) concentration in a suspended solution (P less then 0.05), whereas no significant changes were observed in the As(V) or methyl arsenic acid concentrations. Soil enzyme activity increased and the relative abundances of Proteobacteria and Actinobacteria changed with the addition of FMLBCs.  https://www.selleckchem.com/products/sitagliptin.html  Therefore, the mechanism by which FMLBCs affected As volatilization likely included the following two aspects (1) FMLBCs affected the transformation and distribution of soil As and decreased As dissolution, crystallization, and methylation; (2) FMLBCs influenced soil properties, which directly affected microorganism activity, thereby affecting As volatilization. FMLBCs therefore can decrease As volatilization properties and be used to control As volatilization in As-contaminated paddy soils.Rice husk is a bulky byproduct with a high silica content from rice milling. In this study, the application of an acid-catalyzed ionic liquid (IL) pretreatment was studied for processing rice husks with a rugged structure. The pretreatment conditions were 130°C for 30 min with 1.2 wt% HCl. The results of enzymatic hydrolysis demonstrated that cellulose conversion of HCl-BMIMCl-treated at 48 h was increased by 660.05%, 538.81%, and 376.55% compared with the untreated, HCl-treated, and BMIMCl-treated rice husks, respectively. Composition analysis demonstrated that most of the hemicellulose was removed in the acid-IL combined treatment. Moreover, scanning electron microscopy, X-ray diffraction (XRD), and Fourier transform infrared analyses indicated that the crystalline structure and outer silica layer of the rice husks were efficiently broken up. The results revealed that the HCl-catalyzed dissolution is highly favorable for the industrial application of rick husks in the production of fermentable sugar and high-purity silica.Environmental friendly products particularly natural dyes are going to be much popular around the globe due to their non-toxic and bio-degradable nature. The current study was planned to enhance the dyeability of walnut bark having juglone as a reddish-brown natural dye under ultrasonic radiation as an environment-friendly and green tool After conducting series of experiments, it has been found that wool (RW) and extract (RE) after ultrasonic treatment for 45 min, when dyed for 45 min at 55°C using an acidic bath of 3 pH has given good color strength on the wool fabric. To develop the new shades, sustainable and eco-label chemicals (Fe, Al, and tannic acid) and four bio-mordants such as Acacia bark, Turmeric, Henna, and Pomegranate were also applied at optimum conditions. It is studied that 3% of turmeric extract as pre-bio-mordant and 5% of Acacia extract as post-bio-mordant has given excellent color characteristics as compared to their synthetic. It is concluded that ultrasonic treatment being an eco-friendly tool has a great potential to improve the dyeability of natural reddish-brown dye from walnut bark and the inclusion of sustainable biosources as a color modifier has value-added the natural dyeing process with excellent color ratings.