https://www.selleckchem.com/products/Nolvadex.html Fused-ring electron acceptors have made significant progress in recent years, while the development of fully non-fused ring acceptors has been unsatisfactory. Here, two fully non-fused ring acceptors, o-4TBC-2F and m-4TBC-2F, were designed and synthesized. By regulating the location of the hexyloxy chains, o-4TBC-2F formed planar backbones, while m-4TBC-2F displayed a twisted backbone. Additionally, the o-4TBC-2F film showed a markedly red-shifted absorption after thermal annealing, which indicated the formation of J-aggregates. For fabrication of organic solar cells (OSCs), PBDB-T was used as a donor and blended with the two acceptors. The o-4TBC-2F-based blend films displayed higher charge mobilities, lower energy loss and a higher power conversion efficiency (PCE). The optimized devices based on o-4TBC-2F gave a PCE of 10.26 %, which was much higher than those based on m-4TBC-2F at 2.63 %, and it is one of the highest reported PCE values for fully non-fused ring electron acceptors.We analyzed concentrations and trends of perfluoroalkyl substances (PFAS) in blood plasma samples of bald eagle (Haliaeetus leucocephalus) nestlings at 6 study areas in the upper Midwest of the United States, 2006 to 2015, and long-term trends at 2 Lake Superior (USA/Canada) sites, 1995 to 2015. Nestling blood plasma concentrations of the sum of 15 PFAS analytes (∑PFAS) differed among study areas and were highest at the 3 industrialized river sites pools 3 and 4 of the Mississippi River (pools 3 + 4; geometric mean [GM] = 754 μg/L; range = 633-2930), the Mississippi National River and Recreation Area (GM = 687 μg/L; range = 24-7371), and the lower St. Croix National Scenic Riverway (GM = 546 μg/L; range = 20-2400). Temporal trends in ∑PFAS in nestling plasma differed among study areas; concentrations decreased at pools 3 + 4, Mississippi National River and Recreation Area, and lower St. Croix National Scenic Riverway, but not at the mos