Pesticides are frequently detected in surface waters, sometimes at levels exceeding ecotoxicological guidelines. We screened for almost 100 pesticides in 32 streams from intense agricultural areas in Southern Sweden, in concert with water chemistry parameters. In addition, we investigated the communities of benthic macroinvertebrates, biofilm nematodes and algae and calculated multiple bioassessment metrics. The number of pesticides found in each stream ranged between 2 and 52, but the sum of Toxic Units (ΣTU) for the mixtures was generally low, and exceeded the European Uniform Principles only in a single sample for algae and in 2% of the samples for Daphnia. Only nematode communities were significantly correlated with the ΣTU, potentially due to their higher pesticide exposure in biofilms. Diatom metrics showed that most streams were impacted by eutrophication and macroinvertebrate metrics showed good status in most streams, whereas the SPEARpesticides (SPEcies At Risk) index, specifically designed to indic stressor in the investigated streams, including strong effects of nutrients, less apparent effects of pesticides and likely impact of hydromorphological alterations (not specifically addressed in this study). Microcystin-leucine-arginine (MC-LR), a cyclic potentially carcinogenic hepatotoxin, occurs frequently in aquatic habitats worldwide and seriously threatens ecosystem and public health. Limited effectiveness of physicochemical treatments to remove MC-LR from drinking water has led to a search for alternative cost-effective and environment friendly biodegradation strategies. Obtaining MC-degrading bacteria and understanding their MC-degrading mechanisms are outstanding challenges. Here, a novel indigenous bacterium named Sphingopyxis sp. YF1 with a high efficient capacity for MC-degradation was successfully isolated from eutrophic Lake Taihu. Through integrating mass spectrometer and multi-omics analyses accompanied by functional verification of certain genes and proteins, a complete MC-degradation pathway was firstly identified, in which MC-LR was sequentially degraded into linearized MC-LR, tetrapeptide, Adda, phenylacetic acid, and finally potential product CO2. Some specific proteins such as microcystinase, linearized-microcystinase, tetrapeptidease and PAAase responsible for this pathway were identified. This study pioneeringly demonstrated that MC-LR can be completely degraded through natural remediation processes and revealed a significant potential for MC-LR biodegradation in both natural environment and engineered systems. The sulfate radical (•SO4-)-based advanced oxidation processes (AOPs) for the degradation of refractory organic pollutants consume a large amount of persulfate activators and often generate toxic organic by-products. In this study, we proposed a novel iron-cycling process integrating •SO4--based AOP mediated by reusable iron particles and a sulfidogenic process to degrade and detoxify Orange II completely. The rusted waste iron particles (Fe0@FexOy), which contained FeII/FeIII oxides (FexOy) on the shell and zero-valent iron (Fe0) in the core, efficiently activated persulfate to produce •SO4- and hydroxyl radicals (•OH) to degrade over 95% of Orange II within 120 min. Both •SO4- and •OH destructed Orange II through a sequence of electron transfer, electrophilic addition and hydrogen abstraction reactions to generate several organic by-products (e.g., aromatic amines and phenol), which were more toxic than the untreated Orange II. The AOP-generated organic by-products were further mineralized and detoxified in the toxic by-products. Emission of sulfide and methane from sewerage system has been a major concern for a long time. Sewers are now facing emerging challenges, such as receiving food waste (FW) to relieve the burdens on solid waste treatment. However, the knowledge of the direct impact of FW addition on sulfide and methane production in and emission from sewers is still lacking. In this study, two lab-scale sewer reactors, one without and one with FW addition, were continuously operated to investigate the production of sulfide and methane and microbial communities arising from FW discharge to freshwater sewerage system. The 190-day long-term monitoring and the batch tests on days 69 and 124 suggest that the FW addition has little impact on sulfide production possibly due to the limited sulfate concentration (40 mg S/L) but enhanced methane production by up to 60%. Moreover, cryosection-fluorescence in situ hybridization (FISH) revealed that the FW addition significantly stimulated the accumulation of methanogenic archaea (MA) in sewer biofilms and altered the spatial distributions of sulfate-reducing bacteria (SRB) and MA.  https://www.selleckchem.com/products/plx5622.html  Moreover, the relative abundance of MA in biofilms with FW addition was higher than that without FW addition, whereas the relative abundance of SRB was similar. Metabolic pathway analysis for sulfidogenesis and methanogenesis indicates that sufficient substrates derived from the FW addition were biodegraded during fermentation to produce acetate and hydrogen, and consequently facilitate methanogenesis. These findings shed light on the impacts of changes in wastewater compositions (e.g., FW addition) on sulfide and methane production in the freshwater sewerage system for improved policy-making on sewer management. Volatile organic compounds (VOCs) are perceived as serious pollutants due to their great threat to both environment and human health. Recovery and removal of VOCs is of great significance. Herein, novel MOF-199 derived porous carbon materials (MC-T-n) were prepared by using MOF-199 as precursor, glucose as additional carbon source and KOH as activator, and then characterized. Adsorption performance of MC-T-n materials for benzene vapor was investigated. Isotherms of MC-T-n samples towards benzene and water vapor were measured. The adsorption selectivities of benzene/water were estimated by DIH (difference of the isosteric heats) equation. Results indicated that BET surface area and pore volume of MC-T-n materials reached separately 2320 m2/g and 1.05 m3/g. Benzene adsorption capacity of MC-T-n materials reached as high as 12.8 mmol/g at 25 °C, outperforming MOF-199 and some conventional adsorbents. Moreover, MC-T-n materials presented type-V isotherms of water vapor, suggesting their excellent water resistance.