Interestingly, ~50% of esterase/lipase/cytochrome P450 genes enriched by DEHP under aerobic conditions were from Nocardioides, a bacterial genus that has not been previously directly linked to phthalate ester degradation. The results indicate that novel degraders may play an important role in DEHP degradation in natural soil environments. This study provides a better understanding of the phthalate ester biodegradation processes occurring in soil. Dissolved silica and organic matter are major foulants in reverse osmosis (RO) in brackish water treatment. Though the mechanism of inorganic and organic fouling has been clear, combined silica-organic fouling-resistant membrane have been poorly investigated. In this study, we fabricated membranes with different surface charge.  https://www.selleckchem.com/products/trastuzumab-emtansine-t-dm1-.html  More negatively surface charged membrane (-COOH), acrylic acid (AA) membrane was fabricated through redox free radical grafting method. Ethylamine (EA) and ethylenediamine (ED) membranes with neutral or less negative surface charge were fabricated through -CH3 or -NH2 functional groups grafting. The surface modified membranes were characterized in terms of physicochemical properties and antifouling performance. Compared with the pristine membrane, all the modified membranes possessed better salt rejection without sacrificing water permeability. The AA membrane also showed better antifouling property and higher water flux recovery after physical rinsing. On the other hand, fouling on the EA and ED membranes were aggravated. Unlike the gel-like foulant structure on the EA and ED membrane surfaces, the AA membrane presented more disordered granular structure. Analysis of fouling layer has also proved that there was less silica scaling and organic foulants on the AA membrane surface. Despite the outstanding hydrophilicity of the AA membrane, its antifouling property was mainly attributed to the more negative surface charge, according to regression between flux decline and membrane characteristics. Importantly, we proposed that electrostatic interaction was the dominant fouling mechanism in the combined silica-organic fouling. With more negative surface charge, the AA membrane was prone to prevent foulants from depositing and aggravating, so as to mitigate membrane fouling. Our research provides a simple and practical approach to RO membrane fabrication for anti-inorganic and organic. V.This 2-year (2017 and 2018) field study evaluated biochar and nitrogen application rates effect on herbage phosphorus (P) and nitrogen (N) removal from a mixed-grass sward of tall fescue [Schedonorus arundinaceus (Schreb.) Dumort] and Kentucky bluegrass (Poa pratensis L.) irrigated with treated wastewater. Treatments used in this study carried out at the Main Station Field Laboratory, Reno, NV were three biochar application rates (0, 8.9, and 17.8 Mg/ha), and three N rates (0, 80, and 120 kg N/ha) arranged in a 3 × 3 factorial in a randomized complete block design experiment with four replications of each treatment combination. Responses were considered different P  0 kg N/ha (187.8 kg/ha). There was a trend for a biochar × N rate interaction on soil P concentration and it tended to be greater for the combinations 8.9 and 17.8 Mg/ha biochar rates and 80 and 120 kg N/ha rates compared to the unamended control. Even though our study did not reveal a definitive effect of biochar on the major response parameters (biomass, tissue P and N concentrations) evaluated, the trend for a biochar × N rate interaction on soil P concentration offers hope that biochar-amended soils coupled with appropriate N fertilization will be effective in P retention on agricultural landscapes irrigated with treated wastewater. With the development of urbanization, urban areas have become the main sources and sinks of polycyclic aromatic hydrocarbons (PAHs). The effects of human activities on the behaviors of PAHs in urban agglomerations have attracted significant attention. We collected soil samples (n = 330) to investigate the distribution, composition, and sources of 16 PAHs in the Yangtze River Delta Urban Agglomeration using the land resolution of 24 km × 24 km. The concentrations of Σ16PAHs ranged from 21 to 2034 ng/g, with a median value of 124 ± 338 ng/g. The concentrations of PAHs were highest in impervious surfaces (350 ± 352 ng/g), followed by grassland (259 ± 322 ng/g), cropland (254 ± 341 ng/g), forest (190 ± 303 ng/g), and water (68 ± 34 ng/g). PAHs were dominated by medium-molecular-weight components (4 rings PAHs), followed by PAHs with high-molecular-weight (5-6 rings PAHs) and low-molecular-weight (2-3 rings PAHs) components. Fluoranthene, benzo[a]anthracene and chrysene are three major pollutants in YRDUA. A positive matrix factorization model indicated that fossil fuel combustion, coal combustion and volatilization, vehicle emission, and biomass burning were the main sources of PAHs, contributing 36%, 29%, 22%, and 12% of PAH sources, respectively. Urbanization parameters were positively correlated with PAH concentrations. A land use regression (LUR) model integrated with urbanization parameters showed evidence of the strong relationship between measured PAHs and predicted PAHs. These findings together highlighted that land cover types and human activities intensively influenced the PAHs pollution in the highly urbanized zones. V.Increasing applications of engineered nanomaterials (ENMs) warrant lifecycle assessment of their potential toxicity. Herein, we investigated potential phytotoxicity of copper oxide nanoparticles (CuONPs) on seed yield, focusing on particle size- and concentration-dependent responses of multiple antioxidant defense biomarkers, in soil-grown Glycinemax (cv. Kowsar) during its lifecycle. To this end, we synthesized three distinct sizes CuONPs (25, 50 and 250 nm) all with high purity, monoclinic crystal structure, and same surface charge. Each pot received two seeds, placed in soil inoculated with N-fixing bacteria (Rhizobium japonicum) and grown outdoor for 120 days. Our results show lipid peroxidation (MDA) and several antioxidant biomarkers (SOD, CAT, POX, APX) were differentially altered by the copper compound type, concentrations, and their interactions (p  0.65). Soybean seed yield also mirrored particle size- and concentration-dependent inhibition with CuONPs, and inhibition of CuONP-25 was significantly higher than the two larger size CuONPs or Cu2+ ions at all concentrations tested.