5 and with the total dissolved sulphide concentration increasing above 1300 mg S-TDSu/L. Operation at pH above 8 enabled the recovery of over 90% of the sulphur as dissolved sulphide and thus assisted in minimising the formation and release of toxic H2S.A novel plasmonic Ag/AgCl@LaFeO3 (ALFO) photocatalyst was successfully synthesized by a simple in-situ synthesis method with enhanced photocatalytic activity under visible light for harmful algal blooms (HABs) control. The structure, morphology, chemical states, optical and electrochemical properties of the photocatalyst were systematically investigated using a series of characterization methods. Compared with pure LaFeO3 and Ag/AgCl, ALFO-20% owned a higher light absorption capacity and lower electron-hole recombined rate. Therefore, ALFO-20% had higher photocatalytic activity with a near 100% removal rate of chlorophyll a within 150 min, whose kinetic constant was 15.36 and 9.61 times faster than those of LaFeO3 and Ag/AgCl. In addition, the changes of zeta potential, cell membrane permeability, cell morphology, organic matter, total soluble protein, photosynthetic system and antioxidant enzyme system in Microcystis aeruginosa (M. aeruginosa) were studied to explore the mechanism of M. aeruginosa photocatalytic inactivation. The results showed that ALFO-20% could change the permeability and morphology of the algae cell membrane, as well as destroy the photosynthesis system and antioxidant system of M. aeruginosa. What's more, ALFO could further degrade the organic matters flowed out after algae rupture and die, reducing the secondary pollution and avoiding the recurrence of HABs.  https://www.selleckchem.com/  Finally, the species of reactive oxygen species (ROS) (mainly •O2- and •OH) produced by ALFO were determined through quenching experiments, and a possible photocatalytic mechanism was proposed. Overall, ALFO can efficiently remove the harmful algae under the visible light, providing a promising method for controlling HABs.Alkyl quaternary ammonium-modified clay minerals, which are common environmentally friendly materials, have been widely studied and applied for the removal of pollutants. However, there are few reports on functionalizing the counterions to expand the application. In this study, the cationic gemini surfactant butane-1,4-bis(dodecyl dimethyl ammonium bromide) (gBDDA) and tetrachloroferrate (FeCl4-) are designed to modify montmorillonite (Mt), and the obtained FeCl4-/Gemini-Mt composite (FeOMt) is used for the removal of nitrate and/or phosphate from aqueous solution. The successful intercalation of gBDDA and favorable loading of FeCl4- into FeOMt are suggested by the characterization results of X-ray diffraction and Raman spectroscopy. Nitrate and/or phosphate are rapidly sequestered, and the respective maximum uptakes of 8.77 (N) and 28.1 (P) mg/g in the binary system are obtained. The phosphate uptake is stably maintained against many coexisting ions, but the nitrate uptake decreases with the increase in ionic strength. FeOMt is reusable and shows comparable uptake for nitrate and phosphate with respect to gBDDA-modified Mt and polymerized ferric chloride. Considering the multi-functionality and facile synthesis, FeOMt shows promising potential in the purification of wastewater contaminated simultaneously by poorly hydrated anions (e.g., ClO4-, TcO4-, etc.) and iron-selective anions (e.g., H2AsO4-, etc.).Continuing our previous research work on a drug delivery system based on combined AC/DC magnetic fields, we have developed a prototype AC/DC magnetic syringe device for stimulation of drug release from drug carriers, with the options of injecting/removing drug carriers. The porous Fe3O4 carrier, in a dose-dependent manner, causes acute oxidative damage and reduces the viability of differentiated SH-SY5Y human neuroblastoma cells, indicating the necessity for its removal once it reaches the therapeutic concentration at the target tissue. The working mechanism of the device consists of three simple steps. First, direct injection of the drug adsorbed on the surface of a carrier via a needle inserted into the targeted area. The second step is stimulation of drug release using a combination of AC magnetic field (a coil magnetised needle with AC current) and permanent magnets (DC magnetic lens outside of the body), and the third step is removal of the drug carriers from the injected area after the completion of drug release by magnetising the tip of the needle with DC current. Removing the drug carriers allows us to avoid possible acute and long term side effects of the drug carriers in the patient's body, as well as any potential response of the body to the drug carriers.Cystic echinococcosis is a widespread zoonosis caused by the larval stage of the tapeworm Echinococcus granulosus. In intermediary hosts, two types of echinococcal cysts can be found fertile, which produce protoscoleces, the infective form of the parasite to dogs; and infertile, that do not present protoscoleces and therefore are not able to continue with the parasite life cycle. The adventitial layer, the local immune response against the cyst, plays an important role in cyst fertility. Grazing cattle can often feature Fasciola hepatica co-infection, a parasite known to modulate the host systemic immune response. In this work the cellular Th1/Th2 immune profiles were evaluated in the adventitial layer of fertile and non-fertile cysts with and without co-infection with Fasciola hepatica. Measuring with immunohistochemistry and qPCR in adventitial layer, we report that non-fertile cysts present higher levels of Th1 cytokines (IFN-γ (P  less then  0.0001) and TNF-α (P  less then  0.05)), and fertile cysts have higher levels of Th2 cytokines (IL-4 (P  less then  0.001)). Co-infection with Fasciola hepatica is associated with a decrease in the expression of IL-4 (P  less then  0.05) and an increase in the expression of IFN-γ (P  less then  0.0001) in the adventitial layer of fertile cysts. Non-fertile cysts were associated with higher levels of Th1 cytokines in the adventitial layer, with IFN-γ expression enhanced by F. hepatica co-infection (P  less then  0.0001), confirming that polyparasitism should be considered in the treatment and control of naturally infected cattle.