Finally, we explain the emergence of community norms through intersubjective interaction. Since all group members can adopt alternatively the second-personal stance to each other, demands are sanctioned and recognized in a triangulation process which explains the emergence of group norms.The present study seeks to investigate the sector-level energy consumption of oil and natural gas and to explore the linkage between economic growth, households, agriculture, industry, power, fertilizers, and commercial sector in Pakistan for the period of 1980-2016. The energy sector of Pakistan is facing severe crisis from the last few years due to inadequate production and supply. Long-lasting deficits of natural gas and oil, the two supreme types of fuel in Pakistan, had detrimental consequences for the growth as well as for the economic development. An autoregressive distributed lag (ARDL) method and Granger causality test under vector error correction model (VECM) were employed to check the association among the variables. Furthermore, the innovative accounting method was used to investigate the responsiveness of each variable to another within the study framework. Empirical results show long-run association among the variables, as oil consumption in the agriculture and power sector show a positive effect on Pakistan's economic growth. Similarly, energy consumption from natural gas in the households and fertilizers as well as in the industry sector has had a constructive association with economic growth. In contrast, energy consumption from oil in the households and industry sectors has adverse association with economic growth, while natural gas consumption in the commercial sector has negative linkage with economic growth. Possible steps should be taken by the Government of Pakistan to enhance the production of oil and natural gas from other alternatives to meet the requirements of these sectors.Thallium (Tl) contamination in natural waters can pose a severe risk to human health. In this study, a magnetically responsive Fe3O4@TiO2 core-shell adsorbent was developed for the effective removal of thallium(I) from water. The isoelectric point of the adsorbent surface was decreased from 6.0 to 4.8 due to the loading of nano-sized TiO2, leading to an enhanced electrostatic interaction between the adsorbent and Tl(I) ions in a wider pH range. The Fe3O4@TiO2 magnetic adsorbent exhibited a threefold higher BET specific surface area compared to pristine Fe3O4 particles. The kinetics study showed that approximately 82% of the maximum Tl(I) loading amount could be achieved within 30 min at the initial Tl(I) concentration of 8 mg/L and adsorbent dosage of 0.1 g/L. The adsorption of Tl(I) was significantly increased with increasing solution pH. The experimental data was better fitted by the Langmuir and Temkin isotherms than the Freundlich isotherm and the maximum adsorption capacity of the magnetic adsorbent was 101.5 mg/g at pH 7.0. The interference of co-existing cations in the Tl(I) adsorption followed the subsequence Cu2+ > Mg2+ > Ca2+ > Na+. The hydroxyl groups bonded on titanium atoms might play a key role in the uptake of Tl(I) ions. During the adsorption, the Tl(I) ions can be effectively adsorbed on the adsorbent surface via the formation of Ti-O-Tl linkages. Graphical Abstract.Feeding 9 billion by 2050 is one of major challenges for researchers.  https://www.selleckchem.com/products/envonalkib.html  Use of diversified crops, nonconventional water resources and rehabilitation of marginal lands are alternate options to produce more food to face climate change projections. Adaptation to climate change through climate smart agriculture practices, agroecology activities, and crop-based management packages can help transform the marginal lands from environmental burdens into productive and economic blocks. This review discusses the recent advancements on specialty group of alternate crops (oil seeds, legumes, cereals, medicinal, lignocellulose, and fruit crops) which can adapt in the marginal environments. Availability of alternate water resources (saline water, treated wastewater) for irrigation cannot be omitted. Crop diversification systems involving drought and salt-tolerant crops are likely to be the key to future agricultural and economic growth in the regions where salt-affected soils exist and/or saline aquifers are pumped for irrigation. These systems may tackle three main tasks sustainable management of land resources and enhancement of per unit productivity; intensification of agroecological practices to increase soil fertility; and improving productivity of marginal lands for diversified climate smart crops. This review explores various aspects of marginal lands and selection of tolerant crop genotypes, crop diversification, and agroecological practices to maximize benefits.(Ce,Zr,La)O2 (CZL) mixed oxide-supported rhodium (Rh) catalysts were prepared by in situ synthesis method. Characterizations were adopted to investigate the relation of structure and metal-support interaction with catalytic behavior of catalysts. The results demonstrate that appropriate Ce/Zr ratio (2/1~1/4) could help to form more homogenous CZL ternary solid solution and promote the formation of more oxygen vacancies and defects (the lattice defects resulting from lattice distortion) in CZL supports, and thereby enhance oxygen storage/release performance. Meanwhile, it strongly affects the interaction between RhOx and CZL supports, which promotes the formation of more active Rh species (Rh0 + Rh3+) and the reduction of the oxygen species in Rh-Ce interface, leading to the enhancement of catalytic performance for HC, CO, and NOx eliminations. Rh/CZL-12 shows the best catalytic activity for HC and NOx eliminations. It could be attributed to the enhanced activation and oxygen mobility of lattice oxygen, which is verified by the results of DOSC measurement.The aim of this study was to investigate the effects of vermicomposting (VC) and thermophilic composting (TC) on the molecular transformation of dissolved organic matter (DOM). Here, the DOM after VC and TC (DOMv and DOMt, respectively) was characterized using electrospray ionization coupled with Fourier transform ion cyclotron resonance mass spectrometry (ESI-FT-ICR-MS). The results indicated that VC could improve the preservation of nitrogen and the humification of DOM compared with TC. Concurrently, VC facilitated the formation of highly oxidized molecules (O/C = 0.4-0.9) by enhancing the oxidation. The aromatized molecules in each component were more easily generated during VC, especially N-containing aromatized molecules (39.4-58.0%), thereby improving the quality of compost products. Furthermore, this study found that VC could reduce the anaerobic microsites in pile, thus increasing nominal oxidation state of carbon (NOSC) of organic matter and promoting the decomposition of high-energy substrates (mainly lipids, NOSC = - 1.