https://www.selleckchem.com/products/AZD2281(Olaparib).html After the 20-year dormant period since Liebeskind's seminal report, triorganosulfonium salts have now proved to be reliably useful surrogates of or complement to organic halides in a variety of transition-metal-catalyzed transformations. By necessity, my group developed Suzuki-Miyaura ring-opening arylation of sulfonium salts of dibenzothiophenes with tetraarylborates and Pd-catalyzed intramolecular C-H/C-S coupling. Following this starting point and experiencing the decent reactivity of sulfonium salts, in order to maximize the synthetic utility of organosulfur compounds, we successfully applied readily available sulfonium salts to Ni-catalyzed coupling with arylzinc reagents, Pd- or photoredox-catalyzed Mizoroki-Heck reaction, Pd-catalyzed alkoxycarbonylation, Pd-catalyzed Miyaura borylation, Ni-catalyzed reductive carboxylation, and Ni-catalyzed zincation. I sincerely hope this Personal Account will facilitate further development of reactions of triorganosulfonium salts which are difficult to achieve using conventional organic (pseudo)halides.While the fascinating field of soft machines has grown rapidly over the last two decades, the materials they are constructed from have remained largely unchanged during this time. Parallel activities have led to significant advances in the field of dynamic polymer networks, leading to the design of three-dimensionally cross-linked polymeric materials that are able to adapt and transform through stimuli-induced bond exchange. Recent work has begun to merge these two fields of research by incorporating the stimuli-responsive properties of dynamic polymer networks into soft machine components. These include dielectric elastomers, stretchable electrodes, nanogenerators, and energy storage devices. In this Minireview, we outline recent progress made in this emerging research area and discuss future directions for the field. The investigation of molecular mechanisms and e