Microplastic particles (MPs) contamination of aquatic environments has raised a growing concern in recent decades because of their numerous potential toxicological effects. Although fish are among the most studied aquatic organisms, reports on MPs ingestion in freshwater environments are still scarce. Thus, there is still much to study to understand the uptake mechanisms, their potential accumulation among the food webs and their ecotoxicological effects. Here, MPs presence in the digestive system of one of the most widespread and commercially exploited freshwater fish, the perch (Perca fluviatilis, Linnaeus 1758), was investigated in four different south-alpine lakes, to assess the extent of ingestion and evaluate its relation to the body health condition. A total of 80 perch specimen have been sampled from the Italian lakes Como, Garda, Maggiore and Orta. Microplastic particles occurred in 86% of the analysed specimens, with average values ranging from 1.24 ± 1.04 MPs fish-1 in L. Como to 5.59 ± 2.61 MPs fish-1 in L. Garda. The isolated particles were mainly fragments, except in L. Como where films were more abundant. The most common polymers were polyethylene, polyethylene terephthalate, polyamide, and polycarbonate, although a high degree of degradation was found in 43% of synthetic particles, not allowing their recognition up to a single polymer. Despite the high number of ingested MPs, fish health (evaluated by means of Fulton's body condition and hepatosomatic index) was not affected. Instead, fullness index showed an inverse linear relationship with the number of ingested particles, which suggests that also in perch MPs presence could interfere with feeding activity, as already described for other taxa.Selenium (Se) radioactive wastes can be disposed through stabilization/solidification (S/S) based on the cementitious matrix on hydration products, where hydrocalumite (Ca2Al-LDH) is expected to play an important role in the retention of SeO42-. Natural organic matters (NOMs) are known to be a risk to affect the transportation and mobility of undesirable chemical species in the pedosphere which receives the low level radioactive wastes (LLW). In the present work, five amino acids were selected as the simplified models of NOMs in the pedosphere to explore their effects on the stability of Ca2Al-LDH after immobilized SeO42- under alkaline conditions. As the loading amount of amino acids on Ca2Al-LDH increasing, release of SeO42- was enhanced in HGly, H2Asp, and H2Cys series, while no enhancement was observed in HPhe and HTrp series. Density functional theory (DFT) calculation predicted ion-exchange of amino acids and CO32- with SeO42- in a unit cell of LDH model. The intercalation of Asp2- and CO32- caused 003 peaks in XRD sharper and d003 decreased from 8.15 Å to 7.70 Å which is assigned to Ca2Al-LDH(Asp, CO3). In H2Cys series, the 003 peaks were kept broad and SeO42- was still relatively maintained in LDH which was caused by the lower amounts of intercalated CO32- in the presence of H2Cys. Amino acids in the interlayer of Ca2Al-LDH have several possible configurations, where the most stable one is prone to be in a horizontal direction through hydrogen bonds and Ca-O chemical bonds. This provides an insight on the stability of selenate immobilized in hydrocalumite, which can be produced in cement disposing in the pedosphere for a long term of burying. Not only carbonate but also small molecular organic matters like amino acids possibly give environmental impact on the mobility of low level anionic radionuclides in LDH.Elevated CO2 concentrations can change the multi-level nutritional relationship of the ecosystem through the cascading effect of the food chain. To date, few studies have investigated the effects of elevated CO2 concentration on the Araneae species through the tritrophic system. Hylyphantes graminicola (Araneae Linyphiidae) is distributed widely in Asia and is a dominant predator in cotton fields. This study investigated chemical components in the food chain of cotton (Gossypium hirsutum)-cotton aphid (Aphis gossypii)-predator (H.  https://www.selleckchem.com/products/gs-9973.html  graminicola) and compared the development, reproduction, and predation of H. graminicola under ambient (400 ppm) and elevated concentration of CO2 (800 ppm). The results showed that the elevated CO2 concentration increased the chemicals of cotton and cotton aphid, but it did not affect the nutrients, development, reproduction, and predation of the spider. However, the survival rate of the spider was significantly decreased in elevated CO2. The results will further our understanding of the role of natural enemies in an environment with elevated CO2 concentration.Understanding the comprehensive effect on crop production and quality, soil acidification, and Cd accumulation and distribution for wheat-rice rotation under N fertilization and continuous straw return is important for proper contaminated agricultural soil management. A 2-year paddy field experiment was conducted to study the effects of above factors change in the Zhejiang province, China. Fertilization treatments included conventional N fertilizer application (N3), 20% reduction of N application (N2), 40% reduction of N application (N1), combined with three portions of straw incorporation all straws retention (N3), half of the straws into the fields (S2), 20% straws retention(S1). The N1 treatments significantly decreased crop yields compared to N2 and N3 treatments. Except for C2-wheat, soil pH generally decreased with increasing N fertilizer input in the order of N1>N2>N3, regardless of how many straws was amended. Moreover, we found that straw addition plus N fertilization had a intersystem impacts on Cd accumulation, distribution and availability. Although total Cd had different trends among 4 experimental seasons, when the N reduced 20% applied, the DTPA-Cd contents were lowest among 3 out of four experimental seasons, except for that of C2-wheat, where N2 treatments ranked the second lower contents. For most seasons, Cd contents in straws were higher than soils and lowest in grains, and S2N2 treatment performed an intermediate value among all treatments. Furthermore, our study demonstrated that S2 or N2 treatments or S2N2 reduced the potential risk of plant diseases and pests with lower disease index, disease cluster rate. Notably, the relative outbreak of pests was remarkably suppressed under S2 treatments, especially S2N2. Thus, these findings demonstrated that in wheat-rice rotation reducing 20% N fertilization with 50% straw returning may be a win-win practice in this region for the equilibrium between agricultural productivity, quality and low Cd polluted risk.