https://www.selleckchem.com/products/dl-thiorphan.html Electrodes with the largest interfacial length of gold/silicon oxide exhibited a 10-times larger HER rate in alkaline electrolytes than those with the smallest interfacial length. The data suggest that at the metal/silicon oxide boundaries, alkaline HER is enhanced through a bifunctional mechanism, which we tentatively relate to the laterally structured electrode geometry and to positive charges present in silicon oxide Both properties change locally the interfacial electric field at the gold/silicon oxide boundary, which, in turn, facilitates a faster transport of hydroxide ions away from the electrode/electrolyte interface in alkaline solution. This mechanism boosts the alkaline HER activity of p-type silicon based photoelectrodes close to their HER activity in acidic electrolytes.We present an overview of the variational and diffusion quantum Monte Carlo methods as implemented in the casino program. We particularly focus on developments made in the last decade, describing state-of-the-art quantum Monte Carlo algorithms and software and discussing their strengths and weaknesses. We review a range of recent applications of casino.The solution enthalpy of oxygen in liquid Na was calculated as a test case for the computational method to evaluate the solution enthalpy in liquid metal using first-principles calculations. To obtain the necessary thermodynamic quantities at high temperatures, (i) first-principles molecular dynamics for pure and O-including liquid Na systems, (ii) vibration analysis for an O2 molecule, and (iii) phonon-based quasi-harmonic approximation for solid Na and Na2O were conducted. The calculation results were compared with available experimental data to validate the method. Consequently, the O2 solution enthalpy was calculated to be -387.1 kJ/mol at 600 K and -374.0 kJ/mol at 1000 K, comparable to the experimental data of -375.7 kJ/mol at 600 K and -369.3 kJ/mol at 1000 K. The Na2O solution