https://www.selleckchem.com/TGF-beta.html The emotional benefits of nature among children and adults are well documented. However, little is known regarding how nature exposure influences a parent and child walking together (Journal of Planning Literature, 2015, 30, 433). We examine how both environmental setting and social context influence affect and conversational content among mother-daughter dyads. Twenty-eight mother-daughter (aged 10-12) dyads participated in a within-subjects experimental design that included two counterbalanced conditions-a 20 minute walk outdoors and a 20 minute walk indoors. Self-reported positive affect and negative affect were collected before and after each condition, and audio-recorded observations were utilized to code expressed positivity, negativity, and conversational content during each condition. Results showed that 1) daughters self-reported positive affect increased after the outdoor walk and mothers and daughters reported decreased negative affect after both conditions, 2) mothers and daughters expressed less negativity during the nature walk and were more likely to influence each other's negative affect indoors, and 3) mothers and daughters talked more about the surrounding environment during the indoor walk and engaged in more neutral conversations during the outdoor walk. Findings from the study demonstrate the benefits of mother-daughter dyads walking together outdoors and highlight the importance of spending time outside as a way to promote positive family interactions.A series of functionalized quinoline-based aromatic oligoamide foldamers were prepared in their two enantiomeric forms, comprising an enantiopure terminal camphanyl chiral inducer, which governed the adjacent (P-/M-) helical-handedness. Hierarchical chirality transfer was further investigated in chromophore-appended variants via a range of electronic and vibrational spectroscopic techniques, including circularly polarized luminescence, vibrational circular