Conventional theoretical models such as the rule of mixture and foam model were used to analyze the micromechanics of low-strain (2%) mechanical response (σ). The interdependence of impact toughness, ductility ratio, and domain size of the dispersed rubber phase in the PA410/POE-g-MA blends could successfully be established vis-à-vis the mechanistic role of interparticle distance. Scanning electron microscopy showing domain coalescence of the soft elastomeric POE phase thus reiterated the pivotal role of interdomain distance and domain size in influencing the toughening mechanism of PA410/POE-g-MA blends. The qualitative phase distribution attributes based on atomic force microscopy remained in sync with quantitative parameters, such as domain size, hence reaffirming the mechanism behind ultratoughening of PA410 by POE. Copyright © 2020 American Chemical Society.The clinical impact and accessibility of 99mTc tracers for cancer diagnosis would be greatly enhanced by the availability of a new, simple, and easy labeling process and radiopharmaceuticals. In this study, Technetium-99m-imatinib mesylate ([99mTc]TcIMT) was developed and prepared as a new radiopharmaceutical for breast cancer diagnosis. The effect of critical process parameters on the product quality and stability of [99mTc]TcIMT was investigated using the quality by design concept of the ICH Q8 (Pharmaceutical Development) guideline. [99mTc]TcIMT was subjected to in vitro cell binding studies to determine healthy and cancer cell affinity using HaCaT and MCF-7 cells, respectively. The optimal radiolabeling procedure with 1 mg of IMT, 500 μg of stannous chloride, 0.1 mg of ascorbic acid, and 1mCi 99mTc radioactivity was obtained for [99mTc]TcIMT. The pH of the reaction mixture was adjusted to 10 and allowed to react for 15 min at room temperature. The radiochemical purity of [99mTc]TcIMT was found to be higher than 90% at room temperature up to 6 h. Chromatography analysis revealed >85% [99mTc]TcIMT complex formation with promising stability in saline, cell medium, and serum up to 6 h. The radiolabeled complex showed a higher cell-binding ratio to MCF-7 cells (88.90% ± 3.12) than HaCaT cells (45.64 ± 4.72) when compared to 99mTc. Our findings show that the developed preparation method for [99mTc]TcIMT falls well within the proven acceptable ranges. Applying quality by design (QbD) principles is feasible and worthwhile for the preparation of [99mTc]TcIMT. In conclusion, radiochemical purity, stability, and in vitro cell binding evaluation of the [99mTc]TcIMT complex indicate that the agent can be utilized for imaging of breast cancer cells. Copyright © 2020 American Chemical Society.Since large amounts of pineapple leaves are abandoned after harvest in agricultural areas, the possibility of developing value-added products from them is of interest. In this work, cellulose fiber was extracted from pineapple leaves and modified with ethylenediaminetetraacetic acid (EDTA) and carboxymethyl (CM) groups to produce Cell-EDTA and Cell-CM, respectively, which were then used as heavy metal ion adsorbents. A solution of either lead ion (Pb2+) or cadmium ion (Cd2+) was used as wastewater for the purpose of studying adsorption efficiencies. The adsorption efficiencies of Cell-EDTA and Cell-CM were significantly higher than those of the unmodified cellulose in the pH range 1-7.  https://www.selleckchem.com/products/cb-839.html  Maximum adsorptions toward Pb2+ and Cd2+ were, for Cell-EDTA, 41.2 and 33.2 mg g-1, respectively, and, for Cell-CM, 63.4 and 23.0 mg g-1, respectively. The adsorption behaviors of Cell-CM for Pb2+ and Cd2+ fitted well with a pseudo-first-order model, but those of Cell-EDTA for Pb2+ and Cd2+ fitted well with a pseudo-second-order model. All of the adsorption behaviors could be described using the Langmuir adsorption isotherm. Desorption studies of Pb2+ and Cd2+ on both adsorbents using 1 M HCl suggested that regenerability of Cell-EDTA was, for both adsorbates, better than that of Cell-CM. Moreover, adsorption measurements in a mixture of Pb2+ and Cd2+ at various ratios showed that for both adsorbents the adsorption of Pb2+ was higher than that of Cd2+, while the adsorption selectivity for Pb2+ of Cell-CM was greater than that of Cell-EDTA. This study showed that the modified cellulosic adsorbents made from pineapple leaves were able to efficiently adsorb metal ions. Copyright © 2020 American Chemical Society.To surmount incompatibility provoked efficiency suppression of an anisotype heterojunction and to pursue an improved intrinsic photocatalytic activity by manipulating oriented transfer of photoinduced charge carriers, an In2S3/BiVO4 (11) n-n isotype heterojunction was fabricated successfully through a simple two-step calcination method, followed by a wet-chemical deposition method. The formation of an n-n isotype heterojunction was confirmed by X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and UV-visible diffuse reflectance spectroscopy. The photocatalytic efficiency of the In2S3/BiVO4 catalyst was examined over degradation of oxytetracycline hydrochloride (O-TCH) and oxygen (O2) evolution reaction. Consequently, an n-n In2S3/BiVO4 isotype heterojunction exhibits a superior O-TCH degradation efficiency (94.6%, 120 min) and O2 evolution (695.76 μmol, 120 min) of multiple folds as compared to the pure BiVO4 and In2S3 solely. This is attributed to the proper band aas established, and a possible mechanistic pathway was presented to better understand the outcome of the n-n isotype heterojunction. This study presents an effective way to develop new n-n isotype heterojunction-based efficient photocatalysts and could enrich wide applications in other areas. Copyright © 2020 American Chemical Society.Polymer flooding is one of the most incipient chemical-based enhanced oil recovery process that utilizes the injection of polymer solutions into oil reservoirs. The presence of a polymer in water increases the viscosity of the injected fluid, which upon injection reduces the water-to-oil mobility ratio and the permeability of the porous media, thereby improving oil recovery. The objective of this work is to investigate strategies that would help increase oil recovery. For that purpose, we have studied the effect of injection pressure and increasing polymer concentration on flooding performance. This work emphasizes on the development of a detailed mathematical model describing fluid saturations, pressure, and polymer concentration during the injection experiments and predicts oil recovery. The mathematical model developed for simulations is a black oil model consisting of a two-phase flow (aqueous and oleic) of polymeric solutions in one-dimensional porous media as a function of time and z-coordinate. The mathematical model consisting of heterogeneous, nonlinear, and simultaneous partial differential equations efficiently describes the physical process and consists of various parameters and variables that are involved in our lab-scale process to quantify and analyze them.