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https://www.selleckchem.com/products/epz015666.html The only nonsuperconducting rhenium-silicon binary compound, ReSi1.75, was heavily p-doped with Ga and Al into ReGaSi and ReAlSi in an attempt to evoke superconductivity. They were synthesized and their crystal structures were studied by both X-ray and neutron diffraction. Si and Ga/Al atoms are ordered into alternating layers, which was rationalized with the "coloring problem" study via first-principles calculations. ReGaSi cannot be further p-doped with more Ga, but ReAlSi can be doped with more Al to ReAl1.2Si0.8, in which Si and Al atoms are not ordered but randomly distributed on the same sites. The superconductivity measurements over these compounds demonstrate that the ordered ReAlSi and ReGaSi are not bulk superconductors. However, ReAl1.2Si0.8 becomes bulk superconductor with Tc = ∼3.5 K, which has been confirmed by magnetism, resistivity, and specific heat measurements.Injectable hydrogels can serve as therapeutic vehicles and implants for the treatment of various diseases as well as for tissue repair/regeneration. In particular, the horseradish peroxidase (HRP) and hydrogen peroxide (H2O2)-catalyzed hydrogelation system has attracted much attention, due to its ease of handling and controllable gel properties. In this study, we introduce calcium peroxide (CaO2) as a H2O2-generating reagent to gradually supply a radical source for the HRP-catalyzed crosslinking reaction. This novel therapy can create stiff hydrogels without compromising the cytocompatibility of the hydrogels due to the use of initially high concentrations of H2O2. The physico-chemical properties of the hydrogels can be controlled by varying the concentrations of HRP and CaO2. In addition, the controlled and sustained release of bioactive molecules, including H2O2, O2, and Ca2+ ions, from the hydrogels could stimulate the cellular behaviors (attachment, migration, and differentiation) of human mesenchymal stem cells. Moreover, the hydrogels
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