Yam Code
Sign up
Login
New paste
Home
Trending
Archive
English
English
Tiếng Việt
भारत
Sign up
Login
New Paste
Browse
https://www.selleckchem.com/products/PTC124.html A redox active Ni-Pd alloy nanocluster [Ni22-xPd20+x(CO)48]6- (x = 0.62) ([1]6-) was obtained from the redox condensation of [NBu4]2[Ni6(CO)12] with 0.7-0.8 equivalents of Pd(Et2S)2Cl2 in CH2Cl2. Conversely, [Ni29-xPd6+x(CO)42]6- (x = 0.09) ([2]6-) and [Ni29+xPd6-x(CO)42]6- (x = 0.27) ([3]6-) were obtained by employing [NEt4]2[Ni6(CO)12] and 0.6-0.7 equivalents of Pd(Et2S)2Cl2 in CH3CN. The molecular structures of these high nuclearity Ni-Pd carbonyl clusters were determined by single-crystal X-ray diffraction (SC-XRD). [1]6- adopted an M40 ccp structure comprising five close-packed ABCAB layers capped by two additional Ni atoms. Conversely, [2]6- and [3]6- displayed an hcp M35 metal core composed of three compact ABA layers. [1]6-, [2]6- and [3]6- showed nanometric sizes, with the maximum lengths of their metal cores being 1.3 nm ([1]6-) and 1.0 nm ([2]6- and [3]6-), which increased up to 1.9 and 1.5 nm, after including also the CO ligands. Ni-Pd distribution within their metal cores was achieved by avoiding terminal Pd-CO bonding and minimizing Pd-CO coordination. As a consequence, site preference and partial metal segregation were observed, as well as some substitutional and compositional disorders. Electrochemical and spectroelectrochemical studies revealed that [1]6- and [2]6- were redox active and displayed four and three stable oxidation states, respectively. Even though several redox active high nuclearity metal carbonyl clusters have been previously reported, the nanoclusters described herein represent the first examples of redox active Ni-Pd carbonyl alloy nanoclusters.This study investigated the properties of Scy p 9 in mud crab (Scylla paramamosain). The gene sequence of filamin C obtained from crabs, which was denoted as Scy p 9, contains a 2544 bp open reading frame and encodes 848 amino acid residues. Recombinant Scy p 9 (rScy p 9) is expressed in Escherichia coli, which exhibits tertiary structure chan
Paste Settings
Paste Title :
[Optional]
Paste Folder :
[Optional]
Select
Syntax Highlighting :
[Optional]
Select
Markup
CSS
JavaScript
Bash
C
C#
C++
Java
JSON
Lua
Plaintext
C-like
ABAP
ActionScript
Ada
Apache Configuration
APL
AppleScript
Arduino
ARFF
AsciiDoc
6502 Assembly
ASP.NET (C#)
AutoHotKey
AutoIt
Basic
Batch
Bison
Brainfuck
Bro
CoffeeScript
Clojure
Crystal
Content-Security-Policy
CSS Extras
D
Dart
Diff
Django/Jinja2
Docker
Eiffel
Elixir
Elm
ERB
Erlang
F#
Flow
Fortran
GEDCOM
Gherkin
Git
GLSL
GameMaker Language
Go
GraphQL
Groovy
Haml
Handlebars
Haskell
Haxe
HTTP
HTTP Public-Key-Pins
HTTP Strict-Transport-Security
IchigoJam
Icon
Inform 7
INI
IO
J
Jolie
Julia
Keyman
Kotlin
LaTeX
Less
Liquid
Lisp
LiveScript
LOLCODE
Makefile
Markdown
Markup templating
MATLAB
MEL
Mizar
Monkey
N4JS
NASM
nginx
Nim
Nix
NSIS
Objective-C
OCaml
OpenCL
Oz
PARI/GP
Parser
Pascal
Perl
PHP
PHP Extras
PL/SQL
PowerShell
Processing
Prolog
.properties
Protocol Buffers
Pug
Puppet
Pure
Python
Q (kdb+ database)
Qore
R
React JSX
React TSX
Ren'py
Reason
reST (reStructuredText)
Rip
Roboconf
Ruby
Rust
SAS
Sass (Sass)
Sass (Scss)
Scala
Scheme
Smalltalk
Smarty
SQL
Soy (Closure Template)
Stylus
Swift
TAP
Tcl
Textile
Template Toolkit 2
Twig
TypeScript
VB.Net
Velocity
Verilog
VHDL
vim
Visual Basic
WebAssembly
Wiki markup
Xeora
Xojo (REALbasic)
XQuery
YAML
HTML
Paste Expiration :
[Optional]
Never
Self Destroy
10 Minutes
1 Hour
1 Day
1 Week
2 Weeks
1 Month
6 Months
1 Year
Paste Status :
[Optional]
Public
Unlisted
Private (members only)
Password :
[Optional]
Description:
[Optional]
Tags:
[Optional]
Encrypt Paste
(
?
)
Create New Paste
You are currently not logged in, this means you can not edit or delete anything you paste.
Sign Up
or
Login
Site Languages
×
English
Tiếng Việt
भारत