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https://www.selleckchem.com/products/Y-27632.html Just as expected, NUC-25 exhibits greatly high catalytic activity for the cycloaddition reaction of epoxides with CO2 into alkyl cyclic carbonates under bland solvent-free conditions, which should be ascribed to the polarity of nitrogen-containing pyridine heterocycles as Lewis base sites on the inner surface of nano-caged voids except for recognized Lewis acid sites of rare earth cations. Moreover, the excellent pore-size-dependent catalytic property for Knoevenagel condensation reactions confirms that NUC-25 can be viewed as a recyclable bifunctional heterogeneous catalyst. Therefore, these results strongly demonstrate that microporous MOFs assembled from pre-designed polycarboxyl-heterocyclic ligands display better catalytic performance not only for chemical CO2 fixation but also for Knoevenagel condensation reactions.Although the water-triggered bending behavior of bilayer films has been a wide concerned, there are few reports on wettability-controlled directional actuators with visible color changes. Using photonic crystals as carriers, bilayer directional bending structural color actuators were prepared based on the hydrophilic difference. Top inverse opal with strong hydrophilicity can promote water penetration and strengthen the effect of swelling. While, bottom inverse opal with weak hydrophilicity can inhibit water penetration and weaken the effect of swelling. When the bilayer structure is immersed in water, its wettability differences will produce different optical responses for visualization and will bring different swelling performances, resulting in directional bending. Infiltration differences are visualized as structural color red shifts or transparency. The mechanism of the design involves optical diffractions in the fabricated periodic nanostructures, differences in the surface wettability and swelling rate, uses the infiltration and capillary evaporation of water to realize the spectral diversity

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