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https://www.selleckchem.com/products/mdivi-1.html Using electrospray ion beam deposition, we collide the complex molecule Reichardt's dye (C_41H_30NO^+) at low, hyperthermal translational energy (2-50 eV) with a Cu(100) surface and image the outcome at single-molecule level by scanning tunneling microscopy. We observe bond-selective reaction induced by the translational kinetic energy. The collision impulse compresses the molecule and bends specific bonds, prompting them to react selectively. This dynamics drives the system to seek thermally inaccessible reactive pathways, since the compression timescale (subpicosecond) is much shorter than the thermalization timescale (nanosecond), thereby yielding reaction products that are unobtainable thermally.Organic-inorganic hybrid materials (OIHMs), such as methylammonium lead triiodide (MAPbI3), have a wide composition space because of the various potential combinations of organic molecules and inorganic cages. However, for unknown OHIMs, it is difficult to predict what kind of crystal structure will be stable without any experimental data. In this work, we report an efficient scheme for predicting crystal structures and phase diagrams of MA-Pb-I systems from first-principles calculations and genetic algorithms. In our scheme, OIHMs are divided into organic molecules and inorganic clusters. A pseudobinary phase diagram of MAI-PbI2 was obtained by predicting structures at each composition. These results indicated that only MAPbI3 and MA2PbI4 are stable phases, consistent with the experiments. In addition, the electronic and optical properties of the predicted structures were calculated and the solar cell performance was evaluated. Thus, our method allowed us to search for unknown OIHMs without any experimental data.Nanocellulose fibers bioengineered by bacteria are a high-performance three-dimensional cross-linked network which can confine a dispersed liquid medium such as water. The strong chemical and physical interaction
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