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https://www.selleckchem.com/products/XL184.html The formed BAIL-water nano-interfaces in reverse μEs have exerted a positive effect on the catalytic activity of Cyt-c stored in a water pool of reverse μEs. A five-fold higher rate constant in μEs as compared to buffer establishes μEs as a better catalytic medium. Furthermore, the differing nature of nano-interfaces created by BAILs and water in reverse μEs, depending on the functionalization of the alkyl chain of the cationic part of BAIL, has exerted varying influence on the catalytic activity of Cyt-c. It is expected that the present work will result in providing a versatile platform for the creation of new IL and water based μEs for bio-catalytic applications.Mussel foot proteins (MFPs) strongly adhere to both hydrophilic and hydrophobic surfaces under wet conditions. This water-resistant adhesion of MFP is ascribed to catechol (1,2-dihydroxybenzene) which is highly contained in the MFP. Currently, little is known about the molecular details of the underwater adhesion of catechol onto a nonpolar hydrophobic surface. By using the density functional theory, we investigate the adhesion of catechol onto a wet graphite surface. We unveil the molecular geometry and energy in the course of the wet adhesion of catechol. Catechol adheres through π-π stacking with the underlying graphite. The surrounding water molecules further strengthen the adhesion by forming hydrogen bonds with catechol. In addition, a significant charge transfer has been observed from wet graphite to the catechol. Consequently, catechol adheres onto the present hydrophobic surface as strongly as onto a hydrophilic silica surface.The concept of CO2 switchable deep eutectic solvents (DESs) was proposed and a series of CO2 switchable imidazole-based deep eutectic solvents (DESs) was designed. The CO2 switch mechanism was investigated and the system was used for easy emulsion separation of olive oil from DESs. The benign CO2 switchable DESs have great pote

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