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https://www.selleckchem.com/products/cx-5461.html 3D monolithic reactor has shown great promise for varied heterogeneous catalysis reactions including water treatment, energy generation and storage, and clean fuel production. As a natural porous material, macroporous wood is regarded as an excellent support for inorganic catalyst due to its abundant polar functional groups and channels. On the other hand, a metal organic framework (MOF) has been widely used as heterogeneous catalyst due to its high specific surface area and large amount of microporosities. Combining macroporous wood and a microporous MOF is expected to produce a high-performance 3D reactor and is demonstrated here for Fischer-Tropsch synthesis. The carbonized MOF/wood reactor retains the original cellular structure with over 180 000 channels/cm2. When being decorated with hexagonal-shaped core-shell Co@C nanoparticles aggregates derived from Co-MOF, the MOF/wood reactor resembles a multi-cylinders reactor for Fischer-Tropsch synthesis. Because of the unique combination of macro- and microporous hierarchical structure, the 3D MOF/wood reactor demonstrates exceptional performance under high gas hourly space velocity (81.2% CO conversion and 48.5% C5+ selectivity at 50 L·h-1·gcat-1 GHSV). This validates that MOF/wood can serve as a multi-cylinders and high-power reactor for catalytic reactions, which is expected to be applicable for environmental and energy applications.The combination of area-selective deposition (ASD) with a patternable organic monolayer provides a versatile additive lithography platform, enabling the generation of a variety of nanoscale feature geometries. Stearate hydroxamic acid self-assembled monolayers (SAMs) were patterned with extreme ultraviolet (λ = 13.5 nm) or electron beam irradiation and developed with ASD to achieve line space patterns as small as 50 nm. Density functional theory was employed to aid in the synthesis of hydroxamic acid derivatives with optimized packing d

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