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https://www.selleckchem.com/products/vit-2763.html The high theoretical capacity of red phosphorus (RP) makes it a promising anode material for lithium-ion batteries. However, the large volume change of RP during charging/discharging imposes an adverse effect on the cyclability and the rate performance suffers from its low conductivity. Herein, a facile solution-based strategy is exploited to incorporate phosphorus into the pores of zeolitic imidazole framework (ZIF-8) derived carbon hosts under a mild temperature. With this method, the blocky RP is etched into the form of polyphosphides anions (PP, mainly P5 - ) so that it can easily diffuse into the pores of porous carbon hosts. Especially, the indelible crystalline surface phosphorus can be effectively avoided, which usually generates in the conventional vapor-condensation encapsulation method. Moreover, highly-conductive ZIF-8 derived carbon hosts with any pore smaller than 3 nm are efficient for loading PP and these pores can alleviate the volume change well. Finally, the composite of phosphorus encapsulated into ZIF-8 derived porous carbon exhibits a significantly improved electrochemical performance as lithium-ion battery anode with a high capacity of 786 mAh g-1 after 100 cycles at 0.1 A g-1 , a good stability within 700 cycles at 1 A g-1 , and an excellent rate performance. © 2020 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Chromatin post-translational modifications are thought to be important for epigenetic effects on gene expression. Methylation of histone N-terminal tail lysine residues constitutes one of many such modifications, executed by families of Histone Lysine Methyltransferase (HKMTase). One such protein is ASHH2 from the flowering plant Arabidopsis thaliana, equipped with the interaction domain CW and the HKMTase domain, SET. The CW domain of ASHH2 is a selective binder of monomethylation at Lysine 4 on histone H3 (H3K4me1) and likely helps the enzyme dock correctly ont
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