10%, and the corresponding turbidity removal rate was 93.54%. Further, the mechanism studies suggested that the removal of emulsified oil was realized by the synergistic effects of electric neutralization, demulsification, hydrophobic association and adsorption bridging. The findings of this study showed that nano-TiO2 exhibited a promising prospect in the field of polymer-initiated polymerization.Dielectric barrier discharge (DBD) plasma has been recently used for removal of synthetic organic compounds (SOCs) from aqueous environments. The removal of SOCs by alone DBD is significantly limited by its high electricity needs and inefficient mineralization, which affects the further application of DBD for SOCs. The combined application of DBD with other technologies and the addition of a supplementary substance for energy-saving were proposed to resolve these problems. The addition of catalysts is considered to be a promising and innovative approach to increase the energy yield of DBD, improve the environment friendly of DBD, develop the variety of goal SOCs, and improve the removal efficiency of DBD system. Despite the increasing use of the coupling form of DBD and catalysts, as catalytic dielectric barrier discharge (CDBD), but it still requires a comprehensive review to summarize the last studies and highlight the future perspectives in this area. Therefore, this work is the first literature review aimed to critically assess the latest developments of catalysts coupling with DBD employed in aqueous environments. Moreover, performance evaluation, energy yield, toxicity, eco-friendly, and future perspectives of the CDBD systems for SOCs removal were discussed and overviewed. The results showed that the coupling of catalysts with DBD presents synergistic effects and had excellent removal performance for aqueous SOCs. Overall, it can be concluded that the essential principles of environmental and economic sustainability have been addressed for the removal of persistent pollutants from aqueous environments in the CDBD systems.Sulfate decontamination has drawn widespread attention due to its harmful effects by broad human and animal exposure in recent decades. Adsorption is one of the most promising methods for sulfate decontamination. This review categorized various sulfate adsorbents, discussed the adsorption behavior, and introduced effective adsorbents in detail in terms of their preparation, characterization, and affecting factors on adsorption efficiency. Moreover, adsorption mechanisms of sulfate on different adsorbents are reviewed based on the intermolecular interaction, equilibrium, thermodynamic, and kinetic studies. Among natural bioadsorbents, synthesized-organic, and synthesized-inorganic adsorbents chitin-based shrimp shells (156 mg/g), bagasse pith cellulose-based (526.32 mg/g), and ZrO(OH)2/Y-Zeolite (284.22 mg/g) showed the significant capacity for sulfate uptake from aqueous solution, respectively. Although natural adsorbents have been proved to be inexpensive and efficient, they are not as popular as synthesized adsorbents for sulfate decontamination in recent years due to their low recoverability and reusability. The adsorption mechanism of sulfate to various adsorbents is generally attributed to electrostatic interactions, covalent or ionic bonding, and hydrogen bonding. Based on equilibrium studies, sulfate adsorption processes were done mainly homogeneously for most of the adsorbents; however, there are some exceptions of the heterogeneous adsorption process of sulfate, which is done mostly for adsorbents that remove sulfate through hydrogen and covalent bonding. The kinetic studies illustrated that both film diffusion and pore-diffusion could control sulfate uptake by the various adsorbents. The thermodynamic studies showed that the sulfate adsorption is endothermic and spontaneous except for the sulfate removal by polypyrrole-modified activated-carbons and LDH-HPI mine waste, which requires energy for adsorption.Chlorination is important to the safeness of recouped water; though it shows concern about disinfection by-products (DBPs) formation and its toxic effects. DBPs generation mostly specified by category of disinfectant utilized and naturally occurring organic matter present in the water pre and post disinfection. Plants are exposed to diverse stresses of environment across their lifespan.  https://www.selleckchem.com/products/Cediranib.html  Reactive oxygen species (ROS) perform significant roles in preserving ordinary plant growth and enhancing their tolerance towards stress. This study is focused on the generation and elimination of ROS in apical meristematic growth and responses in Vigna radiata towards DBPs exposure. Phytotoxic and genotoxic effect of selected DBPs, TCAA (trichloroacetic acid), TCM (trichloromethane), TBM (tribromomethane) revealed concentration-dependent root length inhibition, germination index, vigour index, tolerance index, root/shoot ratio with higher EC50 value for TCM (6000 mg/L, 50.26 mM) over TCAA and TBM (1850 mg/L, 11.32 mM; 4000 mg/L, 15.83 mM). DNA laddering assay demonstrated DBP induced DNA damage to be concentration-dependent too. The concentration-dependent increase in the lipid peroxidation, H2O2 generation for each DBPs examined with highest oxidative stress for TCAA over TBM and TCM at fixed concentration illustrates that possible mechanism behind observed toxicity may be via ROS. Its regulation by antioxidative defense enzymes activities can be attributed to observed decline in these enzymes (catalase, ascorbate peroxidase, guaiacol peroxidase) activities with increasing concentration again where TCAA found more significantly affected than TBM and TCM over control. Results thus provide a useful understanding of the mechanism of DBP induced phytotoxicity and genotoxicity in V.radiata.The present study aimed to assess the ecological risk of 30 current-use agricultural pesticides and biocides in the soil, sediments and aquatic organisms of a mixed land-use basin located in the Depressed Pampas Region of Argentina. Risk Quotients (RQs) were used to evaluate the chronic risk in soil and aquatic organisms, while Toxic Units (TUs) were used to assess the acute risk in sediment-dwelling organisms and aquatic biota. Acetochlor, hydroxy-atrazine, glyphosate, AMPA, metolachlor, imidacloprid and tebuconazole were the only pesticide residues detected (>30%) and quantified in all the matrices evaluated. Glyphosate and AMPA showed the highest concentrations, being their mean and maximum levels 27.90-176.00 μg kg-1 and 270-712.50 μg kg-1 in soils, 8.28-32.0 μg kg-1 and 6.85-17.50 μg kg-1 in sediments, and 1.88-4.36 μg L-1 and 0.66-1.03 μg L-1 in surface water. The RQs in soils showed high chronic risk, mainly due to AMPA and imidacloprid. The TUs in sediments showed acute risk in dwelling organisms, mainly due to glyphosate and imidacloprid.