This study describes how potassium salts representative of those in bio ash affect the reactivity of the oxygen carrier ilmenite under moist and dry conditions. Ilmenite is a bench-mark oxygen carrier for chemical-looping combustion, a technique that can separate CO2 from flue gases with minimal energy penalty. Different potassium salts were mixed with ilmenite to a concentration of 4 wt % potassium. The salts used were K2CO3, K2SO4, KCl, and KH2PO4. Experiments were performed at 850 °C under alternately oxidizing and reducing conditions in a dry atmosphere or in the presence of steam. Analyses of the oxygen carrier regarding changes in reactivity, structure, and composition followed the exposures. This study showed that salts such as K2CO3, K2SO4, and KCl increase the reactivity of the ilmenite. For the samples mixed with KCl, most of the salt was evaporated. KH2PO4 decomposed into KPO3, forming layers around the ilmenite particles that lead to agglomeration. Additionally, the KPO3 layer was more or less nonpermeable for CO and decreased the reactivity toward H2 significantly in both dry and wet conditions. This decreased reactivity indicates that the concentration of phosphorus in biofuel may have a significant effect on oxygen carrier degradation. It was also observed that the presence of steam changed the chemistry drastically for the nonphosphorus-containing salts. Alkali salts may react with steam, forming volatile KOH that evaporates partly. KOH may also form K-titanates by reaction with the oxygen carrier, leading to segregation of iron and titanium phases in the ilmenite.
  obesity is defined as excessive accumulation of adipose tissues and is becoming one of the main global severe public health issues. The present study aims to investigate the anti-adipogenesis of laquinimod and the underlying mechanism.
 
  a differentiation cocktail was used to differentiate 3T3-L1 cells, and mice were fed with high fat food to establish the obesity animal model. Oil red O staining, glycerol production assay, and the release of triglyceride were used to evaluate the differentiation degree of 3T3-L1 cells. The expression level of sterol regulatory element binding transcription factor 1 (Srebp1), fatty acid binding protein-4 (FABP4), glucose transporter 4 (GLUT4), peroxisome proliferator-activated receptor-γ (PPAR-γ), CCAAT enhancer-binding proteins (C/EBPα), and phosphorylation of adenosine 5'-monophosphate (AMP)-activated protein kinase α (p-AMPKα) was determined by quantitative real time PCRqRT-PCR and western blot analysis. The pathological state of adipose tissues was evaluated by hematoxylin-eosin staining.
 
  the amount and UV absorption of oil red O, glycerol production, release of triglyceride, and the expression of SREBP1, FABP4, and Glut4 in differentiated 3T3-L1 cells were decreased by the administration of laquinimod. PPAR-γ and C/EBPα were down-regulated, and p-AMPKα was up-regulated by laquinimod. The down-regulated PPAR-γ and C/EBPα, as well as the inhibited lipid accumulation functioned by laquinimod, were reversed by the coincubation with the AMPK inhibitor compound C.  https://www.selleckchem.com/products/gsk2193874.html  Decreased body weight, visceral adipocyte tissue weight, and size of adipocytes were observed in 
  obesity mice after administration with laquinimod.
 
  laquinimod might prevent adipogenesis by down-regulating PPAR-γ and C/EBPα through activating AMPK.
 laquinimod might prevent adipogenesis by down-regulating PPAR-γ and C/EBPα through activating AMPK.A novel, metal-free aerobic oxidation method is described. 4-Dimethylaminopyridine (DMAP) successfully catalyzed the oxidation of aryl α-halo esters to corresponding aryl α-keto esters (up to 95% yield) under mild reaction conditions (Li2CO3, dimethylacetamide, air, and room temperature). A mechanism has been proposed where the oxidation proceeds through a [3 + 2] cycloaddition between O2 in an air atmosphere and pyridinium ylides. The ylides are supposedly generated from aryl α-halo esters and DMAP in the presence of carbonates. Based on the plausible mechanism, the potential of DMAP as a catalyst in oxidation reactions was extended.Limonene is one of the most important terpenes having wide applications in food and fragrance industries. The epoxide of limonene, limonene oxide, finds important applications as a versatile synthetic intermediate in the chemical industry. Therefore, attempts have been made to synthesize limonene oxide using eco-friendly processes because of stringent regulations on its production. In this regard, we have attempted to synthesize it using a cost-effective and eco-friendly process. Chemoenzymatic epoxidation of limonene to limonene oxide was carried out using in situ generation of peroxy octanoic acid from octanoic acid and H2O2. In this study, agricultural-waste rice husk ash (RHA)-derived silica was surface-functionalized using (3-aminopropyl) triethoxysilane (APTS), which was cross-linked using glutaraldehyde for immobilization of Candida antarctica lipase B. Furthermore, the immobilized enzyme was entrapped in calcium alginate beads to avoid enzyme leaching. Thus, limonene oxide was prepared using this catalyst under conventional and microwave heating. The microwave irradiation intensifies the process, reducing the reaction time under the same conditions. Maximum conversion of limonene to limonene oxide of 75.35 ± 0.98% was obtained in 2 h at 50 °C using a microwave power of 50 W. In the absence of microwave irradiation, the conventional heating gave 44.6 ± 1.14% conversion in 12 h. The reaction mechanism was studied using the Lineweaver-Burk plot, which follows a ternary complex mechanism with inhibition due to peroxyoctanoic acid (in other words H2O2). The prepared catalyst shows high reusability and operational stability up to four cycles.In this decade, paper-based microfluidics has gained more interest in the research due to the vast applications in medical diagnosis, environmental monitoring, food safety analysis, etc. In this work, we presented a set of experiments to understand the physics of the capillary flow phenomenon through paper strips. Here, using the wicking phenomenon of the liquid in porous media, experimentally, we find out the capillary height of the liquid in filter paper at different time intervals. It was found that the Lucas-Washburn (L-W) model, as well as the evaporation model, fails to predict the capillary rise accurately. However, the detailed numerical solution shows a better similarity with the experimental results. We have also shown the different regimes of the wicking phenomenon using scaling analysis of the modified L-W model. The capillary rise method was applied to detect the added water content in milk. We used milk as a liquid food and found the added water content from the change in the capillary height at different concentrations of milk.