https://www.selleckchem.com/products/ch6953755.html The second six methane molecules are adsorbed on the remaining L sites, where the C-Hπ interaction becomes important, leading to the synergistic effect together with the C-HO interaction to enhance the adsorption energy of the methane molecule. Finally, it can adsorb up to sixteen CH4 molecules in a single pore of a unit cell at Ni-MOF-74. Moreover, we conducted DOS and EDD analyses, which clearly show that the interactions play a vital role in the adsorption of a methane molecule on Ni-MOF-74, especially the C-HO interaction.Yield-prediction models were studied for efficient exfoliation of soft layered materials stacked via van der Waals interactions with the assistance of machine learning on small experimental data. High-yield exfoliation of graphite and layered organic polymer was achieved under the conditions guided by the models in a limited number of experiments.Tungsten oxide clusters deposited on rutile TiO2 (110) single crystals were used as a model system for heterogenous oxide-oxide bifunctional catalysts. The population of different thermal reaction routes in methanol conversion in the presence of preadsorbed oxygen was probed under UHV conditions. By temperature programmed reaction spectroscopy, we have identified three thermal reaction channels, namely the deoxygenation under formation of methane, the partial oxidation forming formaldehyde and the condensation route under desorption of ethane and dimethyl ether. The specific local reaction environment at the oxidic surface was found to be key for the population of the different reaction channels as exhibited by the introduction of Lewis acidic and basic sites (especially (WO3)n clusters) and available charge carriers such as Ti3+. Especially the amount of bulk Ti3+ interstitials, that can partially transfer charge towards the tungsten oxide clusters at the TiO2 surface, was found to be a key parameter that enables a relatively high methanol conversion