https://www.selleckchem.com/products/incb054329.html These gained insights could help rationally design superior fullerene-perovskite interfaces to achieve high power conversion efficiencies of fullerene-perovskite solar cells.Most cancer cells employ overexpression of glucose transports (GLUTs) to satisfy glucose demand ("Sweet Tooth") for increased aerobic glycolysis rates. GLUT1, one of the most widely expressed GLUTs in numerous cancers, was identified as a prognosis-related biomarker of gastric cancer via tissue array analysis. Herein, a "Sweet Tooth"-oriented SN38 prodrug delivery nanoplatform (Glu-SNP) was developed for targeted gastric cancer therapy. For this purpose, a SN38-derived prodrug (PLA-SN38) was synthesized by tethering 7-ethyl-10-hydroxycamptothecin (SN38) to biocompatible polylactic acid (PLA) with the appropriate degree of polymerization (n = 44). The PLA-SN38 conjugate was further assembled with glycosylated amphiphilic lipid to obtain glucosamine-decorated nanoparticles (Glu-SNP). Glu-SNP exhibited potent antitumor efficiency both in vitro and in vivo through enhanced cancer cell-specific targeting associated with the overexpression of GLUT1, which provides a promising approach for gastric cancer therapy.The involvement of water in the selective oxidation of MAL to MAA over a pure Keggin-type H3PMoO12O40 catalyst was investigated using an in situ DRIFTS reactor coupled with a mass spectrometer for the first time to elucidate the reaction pathway associated with water. Comparing the spectra and activity data using D2O instead of H2O during transient switching experiments has allowed us to evaluate the possible active sites where D2O is activated. It has been found that, during the cycling switches of D2O in and out of the MAL + O2 gas feed at 320 °C, the formation of MAA-OD product is increased and decreased when D2O is added and removed, respectively. This suggests that the deuterium from D2O is involved in the production of gas phase MAA-OD.