Heavy metals, such as Pb(II), Cd(II), Hg(II), do not degrade like organic compounds and remain in soil for a long time. The presence of organic, mineral or polymeric substances (such as polyacrylamides) may contribute to the accumulation and immobilization of toxic metals in poorly absorbable form for living organisms. The main aim of the study was to compare the effectiveness of lead(II) ions immobilization on the layered aluminosilicate surfaces in the anionic polyacrylamide presence. The effectiveness of Pb(II) adsorption was tested depending on metal cation concentration, content of dissociable groups in added flocculant as well as internal structure of clay mineral. The desorption tests of heavy metal ions were performed by the use of water and EDTA (ethylenediaminetetraacetic acid). By means of measurements of suspension stability and aggregate size formed in the studied systems, the flocculating ability of anionic polyacrylamide was checked. The electrokinetic parameters of mineral particles, i.e. surface charge density and electrokinetic potential, without and with individual adsorbates were also determined. It has been shown that the Pb cations adsorbed amount and the effectiveness of their immobilization strongly depends on the polyacrylamide presence in the system and the internal structure of aluminosilicate.For several decades, researchers have been struggling to obtain minimum phosphorus (P) capture costs to meet the parameters for discharging wastewater into the watercourse. Findings from ongoing practices suggest that the Modified University of Cape Town process is currently the cheapest P capture method in the USA, whereas struvite precipitation seems to be the most cost effective method in the rest of the developed world. P sorption via biochars is becoming widespread in developing countries because this technique allows for the turning of voluminous biowaste into fertilizer with soil improving properties. Nevertheless, the reliability of this technology fluctuates throughout the year according to biowaste characteristics. For the first time, it has been proposed to use broken cellulose casings, which are readily available in increasing quantities worldwide. The sorbent obtained was subsequently activated by calcium chloride (CaCl2), whose cost is irrelevant as it would be used for agronomical purposes anyway. Pilot scale experiments show that this novel sorbent is capable of capturing 31.8 kg P t-1 from sludge water that contains 52.5 mg of extractable P L-1. More importantly, it was reported that the novel sorbent captures P, mostly in calcium phosphates (CaP) forms (191.5 g CaP t-1), which are the most valuable for plant nutrition. Enough evidence was obtained to claim that the ongoing technological race to meet the P discharge standards at the lowest cost possible should also reflect the agronomic value of P to plant nutrition to increase its competitiveness.Biomass-derived biochar is a carbon-rich product for soil amendment and sulfapyridine (SPY) is a typical sulfonamide of antibiotics in the soil. Amendment with biochar for soil could control SPY sorption or mobility. However, the pristine biochar inevitably goes through the long-term ageing in the environment and the information on such ageing impact on SPY sorption is not fully recognized. The simulated ageing process methods were employed for high-temperature and freeze-thraw climate to treat the biochar for two months in the present study. The batch adsorption of SPY and leaching column experiments were conducted for comparison of the fresh/aged biochar-soil system. The results showed that biochar addition could increase soil pH and saturated moisture, aged biochars own more O-containing functional groups and exhibit higher hydrophilicity and polarity. The sorption mechanism of unamended soil with SPY primarily resulted from the weak hydrophobic distribution.  https://www.selleckchem.com/products/almorexant-hcl.html  All fresh and aged biochar amended soil increased SPY sorption due to improvement of H-bonding interaction between SPY and biochar surface functional groups, indicating such initiative adsorption was stronger than passive partitioning. It is of importance for us to reconsider that aged biochar-amended soil, especially two-month high-temperature aged biochar-amended soil showed the highest adsorption performance and the lowest desorption capacity towards SPY. Both SPY leaching column experiments and the acid rain leaching tests suggested that the application of biochar in tropical or high-temperature climate regions for organics polluted soil remediation is favorable, but we should be aware of the uncertainty of soil amendment with biochar in cold regions.We examined some possible effects of heavy metal accumulations on bird morphometry. House sparrows Passer domesticus were caught in unpolluted and polluted areas having a thermal power plant, in Turkey. Fifteen different morphometric characters were compared with the heavy metal accumulations of Cu, Co, Zn, Mn, Ni, and Cr in samples from muscle, kidney, and liver. We found positive or negative correlations between some heavy metal accumulations in some tissues and the length of some morphometric characters of sparrows (p less then 0.01). The most correlated heavy metal with as many characters was Zn in muscle and liver, followed by Cu in liver and Cu in muscle. We found mainly negative coefficient values of some heavy metal bioaccumulation for morphometry using stepwise linear regression analysis. Negative coefficient values of Zn accumulation in muscle and the liver for body mass and feathers were found (p less then 0.01). Length of bill and claws were affected by the bioaccumulation; the positive coefficient values of Zn in the muscle and the liver and negative coefficient values of Cu in the kidney for the length of the bill, positive coefficient value of Cu in muscle and the negative coefficient value of Mn in the kidney for length of the claws were found respectively (p less then 0.01). The heavy metal accumulations in the tissues were found to affect morphometric characters' length. The effects of heavy metal accumulations in tissues should be considered in further morphometrical studies of a bird species, especially in polluted areas.