https://www.selleckchem.com/products/euk-134.html 35-41.23% in rice tissues. The use of manure fertilizer increased the soil pH and amount of available Cd in soil, as well as the accumulation of Cd in rice roots. Based on sequential extraction, acid-extractable Cd accounted for approximately 52.54%-61.88% of total Cd in atmospherically deposited particles in the study area, resulting in a high proportion of acid-extractable Cd in soil. This study provides useful reference data on the sources of Cd and its bioavailability in soil and rice.Currently, the interaction between contaminants and dissolved organic matter (DOM) during artificial groundwater recharge (AGR) with effluent from underutilized wastewater treatment plant (WWTP) is unclear. The present study investigated DOM evolution in this AGR scenario. The DOM composition in the inflow was identified to be distinct to that of the outflow due to the release of soil humic acid (HA). The soluble soil HA was then extracted and used in co-transport experiments with tetracycline (TC). The separated HA transport through the soil column exhibited high mobility with mass recovery >92.5% in the effluent. Following the mixing of injected TC and HA, the TC breakthrough in the column increased with HA concentration. TC was heavily adsorbed by the soil without the presence of HA, yet the retention ratios decreased from 63.60% to 53.30% for the HA range of 0-20 mg L-1. An advection-dispersion-retention (ADR) numerical model was developed to effectively quantify the HA-TC co-transport, with results demonstrating the reduction in the TC attachment rate with increasing HA concentrations. Furthermore, batch adsorption experiments, kinetics and isotherms models, and FTIR spectra analysis were implemented to determine the underlying mechanism. The co-transport behavior was observed to be a function of the relative soil sorption affinity between HA and TC. The weaker sorption of the HA-coated TC compared to the separated TC consequen