https://www.selleckchem.com/products/n-ethylmaleimide-nem.html Constructing a rational electrode structure for supercapacitors is critical to accelerate the electrochemical kinetics process and thus promote the capacitance. Focusing on the flexible supercapacitor electrode, we synthesized a three-dimensional (3D) porous polypyrrole (PPy) film using a modified vapor phase polymerization method with the use of a porous template (CaCO3). The porous design provided the PPy film with an improved surface area and pore volume. The porous PPy film electrode was studied as a binder-free electrode for supercapacitors. It was found that the abundant interpenetrated pores created by the CaCO3 templates within the 3D framework are beneficial to overcoming the diffusion-controlled limit in the overall electrochemical process. It was revealed by electrochemical investigation that a more pseudocapacitive contribution than diffusion-controlled process contribution was observed in the total charge in the redox reaction. The galvanostatic charge/discharge (GCD) measurements showed that thend the synthesis of flexible and wearable film electrodes with high performance.Lithium-metal batteries are promising candidates for the next-generation energy storage devices. However, notorious dendrite growth and an unstable interface between Li and electrolytes severely hamper the practical implantation of Li-metal anodes. Here, a robust solid electrolyte interphase (SEI) layer with flexible organic components on the top and plentiful LiF together with lithiophilic Zn nanoparticles on the bottom is constructed on Li metal based on the spray quenching method. The fluorinated interface layer exhibits remarkable stability to shield Li from the aggressive electrolyte and restrain dendrite growth. Accordingly, the modified Li electrode delivers a stable cycling for over 400 cycles at 3 mA cm-2 in symmetric cells. An improved capacity retention is also achieved in a full cell with a LiFePO4 cathode. Th