5Se0.5/SrTiO3(001) but also offer the crucial information for investigating the high-temperature superconductivity in interfacial iron selenides.The near-field of surface plasmon resonances at planar metal surfaces is confined to the nanoscale, but its resonance wavelength is located in the visible light range, making it interesting for confining polymer functionalization of surfaces but incompatible with the majority of polymerization reactions. Here, fluorescein as a polymerization initiator allowing dye-sensitized polymerization with green light (438-540 nm) is demonstrated to allow polymer functionalization of mesoporous films deposited onto planar silver metal layers. The fluorescein-induced polymer functionalization of mesoporous silica films is investigated with respect to the influence of irradiation power and irradiation time and its potential to generate polymer gradients. Finally, the polymer functionalization of mesoporous films upon surface-plasmon-initiated polymerization is demonstrated. Polymer functionalization thereby determines pH-responsive ionic mesopore accessibility.  https://www.selleckchem.com/products/bpv-hopic.html  Consequently, these results present a sound basis for further nanoscale near-field-induced polymer functionalization of porous films.Homogeneously mixing multiple metal elements within a single particle may offer new material property functionalities. High entropy alloys (HEAs), nominally defined as structures containing five or more well-mixed metal elements, are being explored at the nanoscale, but the scale-up to enable their industrial application is an extremely challenging problem. Here, we report an aerosol droplet-mediated technique toward scalable synthesis of HEA nanoparticles with atomic-level mixing of immiscible metal elements. An aqueous solution of metal salts is nebulized to generate ∼1 μm aerosol droplets, which when subjected to fast heating/quenching result in decomposition of the precursors and freezing-in of the zero-valent metal atoms. Atomic-level resolution scanning transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis reveals that all metal elements in the nanoparticles are homogeneously mixed at the atomic level. We believe that this approach offers a facile and flexible aerosol droplet-mediated synthesis technique that will ultimately enable bulk processing starting from a particulate HEA.The facile oxidation of alcohols to carboxylate salts and H2 is achieved using a simple and readily accessible cobalt pincer catalyst (NNNHtBuCoBr2). The reaction follows an acceptorless dehydrogenation pathway and displays good functional group tolerance. The amine-amide metal-ligand cooperation in cobalt catalyst is suggested to facilitate this transformation. The mechanistic studies indicate that in-situ-formed aldehydes react with a base through a Cannizzaro-type pathway, resulting in potassium hemiacetolate, which further undergoes catalytic dehydrogenation to provide the carboxylate salts and H2.A mild, versatile organophotoredox protocol has been developed for the preparation of diverse, enantioenriched α-deuterated α-amino acids. Distinct from the well-established two-electron transformations, this radical-based strategy offers the unrivaled capacity of the convergent unification of readily accessible feedstock carboxylic acids and a chiral methyleneoxazolidinone fragment and the simultaneous highly diastereo-, chemo-, and regioselective incorporation of deuterium. Furthermore, the approach has addressed the long-standing challenge of the installation of sterically demanding side chains into α-amino acids.Brønsted acid-catalyzed addition of the chiral N,N'-dioxide into ynamides generated enolonium ions in situ which underwent enantioselective alkylation by indoles, pyrroles, and phenols, without racemization of the formed tertiary center. This external oxidant approach allows for the use of unmodified nucleophiles and does not leave trace groups from the oxidant, which significantly increases the synthetic efficiency and the product diversity. Furthermore, the byproduct of the N,N'-dioxide could be efficiently recycled into an optically pure form.The structure of adsorbed surfactant layers at the equilibrium state has already been investigated using various experimental techniques. However, the comprehension of the formation of structural intermediates in nonequilibrium states and the resulting adsorption kinetics still remain a challenging task. The temporal characterization of these intermediate structures provides further understanding of the layer structure at equilibrium and of the main interactions involved in the adsorption process. In this article, we studied the adsorption kinetics of AOT vesicles on silica at different pHs at ambient temperature. The AOT vesicles were formed in a brine solution. Quartz crystal microbalance with dissipation monitoring (QCM-D) was used to obtain information on the kinetics of surfactant adsorption and on the structure of the adsorbed layer at the equilibrium state. Additionally, neutron reflectivity experiments were performed to provide a detailed description of the mean surfactant concentration profile normal to the surface at equilibrium. Results suggest that vesicles in the bulk influence the adsorption mechanisms. In acidic conditions, after a time-dependent structural rearrangement step, followed by the rupture of initially adsorbed vesicles, the formation of a bilayer was observed. At an intermediate and basic pH, in spite of the electrostatic repulsion between the negatively charged surfactants and silica, results demonstrated the existence of an adsorbed layer composed of AOT vesicles. Vesicles are more or less closely packed depending on the pH of the solution. Results show a non-negligible influence of NaCl addition at pH values where adsorption is initially inhibited. Vesicle adsorption at the intermediate and basic pH is probably due to the combination of attractive van der Waals interactions promoted in high ionic strength systems and the formation of hydrogen bonds. Interpretation of adsorption kinetics gave insight into adsorption mechanisms in an electrostatic repulsion environment.