https://www.selleckchem.com/products/vu661013.html , ranging broadly from hydrogen bond to dipole-dipole/quadrupole interactions, electrostatic interaction, acid-base interaction, coordination, and electronic interactions. We scrutinize the unique properties and functions of adsorption and separation, catalysis, energy transformation and storage, and proton and metal ion transport by disclosing functional design schemes and interface-function correlations. We predict the fundamental key issues to be addressed and show future directions in designing artificial pores to target at ultimate functions. This chemistry on pore interface engineering opens a way to porous materials that have remained challenging in the predesign of both structure and function.ConspectusPlasmonic nanostructures have garnered widescale scientific interest because of their strong light-matter interactions and the tunability of their absorption across the solar spectrum. At the heart of their superlative interaction with light is the resonant excitation of a collective oscillation of electrons in the nanostructure by the incident electromagnetic field. These resonant oscillations are known as localized surface plasmon resonances (LSPRs). In recent years, the community has uncovered intriguing photochemical attributes of noble metal nanostructures arising from their LSPRs. Chemical reactions that are otherwise unfavorable or sluggish in the dark are induced on the nanostructure surface upon photoexcitation of LSPRs. This phenomenon has led to the birth of plasmonic catalysis. The rates of a variety of kinetically challenging reactions are enhanced by plasmon-excited nanostructures. While the potential utility for solar energy harvesting and chemical production is clear, there is a natulight-induced potentials may be used as a knob for controlling the activities and selectivities of noble metal nanoparticle catalysts.The pH of a solution is one of its most fundamental chemical properties, impactin