Background While there is growing awareness of the need to support the physical and mental wellbeing of transgender people, some may be reluctant to seek help from healthcare professionals. Little is understood about the mechanisms that influence help-seeking behavior in this group. Aims This study aimed to compare transgender and cisgender participants in their likelihood to seek help for both physical and mental health conditions, and to explore whether this help-seeking behavior is predicted by a range of sociodemographic and psychological variables. Methods 123 participants living in Ireland (cisgender= 67; transgender= 56) completed a questionnaire which included demographic questions, as well as measures of optimism (LOT-R), self-esteem (RSES), psychological distress (GHQ-12), attitudes towards seeking psychological help (ATSPPH-SF), and attitudes towards seeking help for a physical health problem (Attitudes Towards Seeking Medical Help Scale- Action/Intervention subscale). Associations between predictoic healthcare and suggests that healthcare professionals should acknowledge the specific healthcare needs and concerns among transgender individuals.In recent decades, the chemistry of stable silylenes (R2Si) has evolved significantly. The first major development in this chemistry was the isolation of a silicocene which is stabilized by the Cp* (Cp* = η5-C5Me5) ligand in 1986 and subsequently the isolation of a first N-heterocyclic silylene (NHSi) in 1994. Since the groundbreaking discoveries, a large number of isolable cyclic silylenes and higher coordinated silylenes, i.e. Si(II) compounds with coordination number greater than two, have been prepared and the properties investigated. However, the first isolable two-coordinate acyclic silylene was finally reported in 2012. The achievements in the synthesis of acyclic silylenes have allowed for the utilization of silylenes in small molecule activation including inert H2 activation, a process previously exclusive to transition metals. This minireview highlights the developments in silylene chemistry, specifically two-coordinate acyclic silylenes, including experimental and computational studies which investigate the extremely high reactivity of the acyclic silylenes.It has been widely acknowledged in debates about nationalism and ethnicity that identity categories used for classifying people along the lines of culture, race, and ethnicity help to enact, that is, bring into being, the collective identities they name. However, we know little about how categories acquire their performative powers. The contribution of this paper is twofold first, it proposes a conceptual framework based on concepts and insights from science and technology studies for investigating the performative powers of statistical identity categories and possibly also other domains.  https://www.selleckchem.com/products/guanidine-thiocyanate.html  Second, it demonstrates, through an empirical study of two examples from Estonian and Dutch official population statistics, that statistical identity categories enact more than the groups to which they refer. We argue that they also enact national identities and notions of national belonging of majoritarian groups in the host countries. Therefore, statistical identity categories can be used as analytical lenses to study nationalism and processes of nation-building.An updated checklist of the ants (Hymenoptera Formicidae) of Sri Lanka is presented. These include representatives of eleven of the 17 known extant subfamilies with 341 valid ant species in 79 genera. Lioponera longitarsus Mayr, 1879 is reported as a new species country record for Sri Lanka. Notes about type localities, depositories, and relevant references to each species record are given. Accounts of the dubious and some undetermined species from Sri Lanka are also provided. 82 species (24%) are endemic whereas 18 species that are non-native to Sri Lanka are recorded. The list provides a synthesis of the regional taxonomical work carried out to date and will serve as a baseline for future studies on the ant fauna of this biodiversity hotspot.Plagioclase feldspar is one of the most common rock-forming minerals on the surfaces of the Earth and other terrestrial planetary bodies, where it has been exposed to the ubiquitous process of hypervelocity impact. However, the response of plagioclase to shock metamorphism remains poorly understood. In particular, constraining the initiation and progression of shock-induced amorphization in plagioclase (i.e., conversion to diaplectic glass) would improve our knowledge of how shock progressively deforms plagioclase. In turn, this information would enable plagioclase to be used to evaluate the shock stage of meteorites and terrestrial impactites, whenever they lack traditionally used shock indicator minerals, such as olivine and quartz. Here, we report on an electron backscatter diffraction (EBSD) study of shocked plagioclase grains in a metagranite shatter cone from the central uplift of the Manicouagan impact structure, Canada. Our study suggests that, in plagioclase, shock amorphization is initially localized either within pre-existing twins or along lamellae, with similar characteristics to planar deformation features (PDFs) but that resemble twins in their periodicity. These lamellae likely represent specific crystallographic planes that undergo preferential structural failure under shock conditions. The orientation of preexisting twin sets that are preferentially amorphized and that of amorphous lamellae is likely favorable with respect to scattering of the local shock wave and corresponds to the "weakest" orientation for a specific shock pressure value. This observation supports a universal formation mechanism for PDFs in silicate minerals.Shocked quartz and feldspar grains commonly exhibit planar microstructures, such as planar fractures, planar deformation features, and possibly microtwins, which are considered to have formed by shock metamorphism. Their orientation and frequency are typically reported to be randomly distributed across a sample. The goal of this study is to investigate whether such microstructures are completely random within a given sample, or whether their orientation might also retain information on the direction of the local shock wave propagation. For this work, we selected samples of shatter cones, which were cut normal to the striated surface and the striation direction, from three impact structures (Keurusselkä, Finland, and Charlevoix and Manicouagan, Canada). These samples show different stages of pre-impact tectonic deformation. Additionally, we investigated several shocked granite samples, selected at different depths along the drill core recovered during the joint IODP-ICDP Chicxulub Expedition 364 (Mexico). In this case, thin sections were cut along two orthogonal directions, one parallel and one normal to the drill core axis.